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Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]

In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetra­methyl­ethane-1,2-di­amine ligand and coordinated by a water mol­ecule as well as bridged by two tetra­bromo­phthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. T...

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Autores principales: Tobón-Trujillo, Luis Manuel, Villanueva-Sánchez, Luis Felipe, Martínez-Otero, Diego, Dorazco-González, Alejandro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555376/
https://www.ncbi.nlm.nih.gov/pubmed/26396871
http://dx.doi.org/10.1107/S2056989015015194
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author Tobón-Trujillo, Luis Manuel
Villanueva-Sánchez, Luis Felipe
Martínez-Otero, Diego
Dorazco-González, Alejandro
author_facet Tobón-Trujillo, Luis Manuel
Villanueva-Sánchez, Luis Felipe
Martínez-Otero, Diego
Dorazco-González, Alejandro
author_sort Tobón-Trujillo, Luis Manuel
collection PubMed
description In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetra­methyl­ethane-1,2-di­amine ligand and coordinated by a water mol­ecule as well as bridged by two tetra­bromo­phthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. The two symmetry-related tetra­bromo­phthalate anions bridge the two Cu(II) cations, forming a centrosymmetric dinuclear complex in which the Cu⋯Cu separation is 5.054 (2) Å. Intra­molecular classic O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds occur in the dinuclear mol­ecule. In the crystal, the mol­ecules are linked by weak C—H⋯Br and C—H⋯O inter­actions into supra­molecular chains propagating along the b-axis direction.
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spelling pubmed-45553762015-09-22 Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)] Tobón-Trujillo, Luis Manuel Villanueva-Sánchez, Luis Felipe Martínez-Otero, Diego Dorazco-González, Alejandro Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetra­methyl­ethane-1,2-di­amine ligand and coordinated by a water mol­ecule as well as bridged by two tetra­bromo­phthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. The two symmetry-related tetra­bromo­phthalate anions bridge the two Cu(II) cations, forming a centrosymmetric dinuclear complex in which the Cu⋯Cu separation is 5.054 (2) Å. Intra­molecular classic O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds occur in the dinuclear mol­ecule. In the crystal, the mol­ecules are linked by weak C—H⋯Br and C—H⋯O inter­actions into supra­molecular chains propagating along the b-axis direction. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555376/ /pubmed/26396871 http://dx.doi.org/10.1107/S2056989015015194 Text en © Tobón-Trujillo et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Tobón-Trujillo, Luis Manuel
Villanueva-Sánchez, Luis Felipe
Martínez-Otero, Diego
Dorazco-González, Alejandro
Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title_full Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title_fullStr Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title_full_unstemmed Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title_short Crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetra­methyl­ethane-1,2-di­amine-κ(2) N,N′)copper(II)]
title_sort crystal structure of bis­(μ(2)-tetra­bromo­phthalato-κ(2) o (1):o (2))bis[aqua(n,n,n′,n′-tetra­methyl­ethane-1,2-di­amine-κ(2) n,n′)copper(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555376/
https://www.ncbi.nlm.nih.gov/pubmed/26396871
http://dx.doi.org/10.1107/S2056989015015194
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