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Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2) N,N′)copper(II)]
In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetramethylethane-1,2-diamine ligand and coordinated by a water molecule as well as bridged by two tetrabromophthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555376/ https://www.ncbi.nlm.nih.gov/pubmed/26396871 http://dx.doi.org/10.1107/S2056989015015194 |
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author | Tobón-Trujillo, Luis Manuel Villanueva-Sánchez, Luis Felipe Martínez-Otero, Diego Dorazco-González, Alejandro |
author_facet | Tobón-Trujillo, Luis Manuel Villanueva-Sánchez, Luis Felipe Martínez-Otero, Diego Dorazco-González, Alejandro |
author_sort | Tobón-Trujillo, Luis Manuel |
collection | PubMed |
description | In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetramethylethane-1,2-diamine ligand and coordinated by a water molecule as well as bridged by two tetrabromophthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. The two symmetry-related tetrabromophthalate anions bridge the two Cu(II) cations, forming a centrosymmetric dinuclear complex in which the Cu⋯Cu separation is 5.054 (2) Å. Intramolecular classic O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds occur in the dinuclear molecule. In the crystal, the molecules are linked by weak C—H⋯Br and C—H⋯O interactions into supramolecular chains propagating along the b-axis direction. |
format | Online Article Text |
id | pubmed-4555376 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45553762015-09-22 Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2) N,N′)copper(II)] Tobón-Trujillo, Luis Manuel Villanueva-Sánchez, Luis Felipe Martínez-Otero, Diego Dorazco-González, Alejandro Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [Cu(2)(C(8)Br(4)O(4))(2)(C(6)H(16)N(2))(2)(H(2)O)(2)], the Cu(II) cation is chelated by a tetramethylethane-1,2-diamine ligand and coordinated by a water molecule as well as bridged by two tetrabromophthalate anions in a distorted O(3)N(2) trigonal–bipyramidal geometry. The two symmetry-related tetrabromophthalate anions bridge the two Cu(II) cations, forming a centrosymmetric dinuclear complex in which the Cu⋯Cu separation is 5.054 (2) Å. Intramolecular classic O—H⋯O hydrogen bonds and weak C—H⋯O hydrogen bonds occur in the dinuclear molecule. In the crystal, the molecules are linked by weak C—H⋯Br and C—H⋯O interactions into supramolecular chains propagating along the b-axis direction. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555376/ /pubmed/26396871 http://dx.doi.org/10.1107/S2056989015015194 Text en © Tobón-Trujillo et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Tobón-Trujillo, Luis Manuel Villanueva-Sánchez, Luis Felipe Martínez-Otero, Diego Dorazco-González, Alejandro Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2) O (1):O (2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2) N,N′)copper(II)] |
title | Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
O
(1):O
(2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2)
N,N′)copper(II)] |
title_full | Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
O
(1):O
(2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2)
N,N′)copper(II)] |
title_fullStr | Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
O
(1):O
(2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2)
N,N′)copper(II)] |
title_full_unstemmed | Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
O
(1):O
(2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2)
N,N′)copper(II)] |
title_short | Crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
O
(1):O
(2))bis[aqua(N,N,N′,N′-tetramethylethane-1,2-diamine-κ(2)
N,N′)copper(II)] |
title_sort | crystal structure of bis(μ(2)-tetrabromophthalato-κ(2)
o
(1):o
(2))bis[aqua(n,n,n′,n′-tetramethylethane-1,2-diamine-κ(2)
n,n′)copper(ii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555376/ https://www.ncbi.nlm.nih.gov/pubmed/26396871 http://dx.doi.org/10.1107/S2056989015015194 |
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