Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)

The title compound, [Pd(C(11)H(8)N)(C(6)H(10)NS(2))], crystallizes with three similar and discrete mol­ecules in the asymmetric unit. The CNS(2) donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands...

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Autores principales: Kondrashov, Mikhail, Fleckhaus, André, Gritcenko, Roman, Wendt, Ola F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555382/
https://www.ncbi.nlm.nih.gov/pubmed/26396868
http://dx.doi.org/10.1107/S2056989015015005
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author Kondrashov, Mikhail
Fleckhaus, André
Gritcenko, Roman
Wendt, Ola F.
author_facet Kondrashov, Mikhail
Fleckhaus, André
Gritcenko, Roman
Wendt, Ola F.
author_sort Kondrashov, Mikhail
collection PubMed
description The title compound, [Pd(C(11)H(8)N)(C(6)H(10)NS(2))], crystallizes with three similar and discrete mol­ecules in the asymmetric unit. The CNS(2) donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C—Pd—N angles are all around 81° and the S—Pd—S angles are around 75°. Mol­ecules pack via dispersion inter­actions.
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spelling pubmed-45553822015-09-22 Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II) Kondrashov, Mikhail Fleckhaus, André Gritcenko, Roman Wendt, Ola F. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, [Pd(C(11)H(8)N)(C(6)H(10)NS(2))], crystallizes with three similar and discrete mol­ecules in the asymmetric unit. The CNS(2) donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C—Pd—N angles are all around 81° and the S—Pd—S angles are around 75°. Mol­ecules pack via dispersion inter­actions. International Union of Crystallography 2015-08-15 /pmc/articles/PMC4555382/ /pubmed/26396868 http://dx.doi.org/10.1107/S2056989015015005 Text en © Kondrashov et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kondrashov, Mikhail
Fleckhaus, André
Gritcenko, Roman
Wendt, Ola F.
Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title_full Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title_fullStr Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title_full_unstemmed Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title_short Crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II)
title_sort crystal structure of (piperidine-1-carbo­di­thio­ato-κ(2) s,s)[2-(pyridin-2-yl)phenyl-κ(2) c (1),n]palladium(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555382/
https://www.ncbi.nlm.nih.gov/pubmed/26396868
http://dx.doi.org/10.1107/S2056989015015005
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