Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)

The asymmetric unit of the title compound, (C(4)H(7)N(2))(2)[CoCl(4)], consists of two 2-methyl­imidazolium cations and one tetra­hedral [CoCl(4)](2−) anion. The anions and cations inter­act through N—H⋯Cl hydrogen bonds to define layers with a stacking direction along [100]. Besides van der Waals f...

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Detalles Bibliográficos
Autores principales: Diop, Mouhamadou Birame, Diop, Libasse, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555386/
https://www.ncbi.nlm.nih.gov/pubmed/26396849
http://dx.doi.org/10.1107/S2056989015014127
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author Diop, Mouhamadou Birame
Diop, Libasse
Maris, Thierry
author_facet Diop, Mouhamadou Birame
Diop, Libasse
Maris, Thierry
author_sort Diop, Mouhamadou Birame
collection PubMed
description The asymmetric unit of the title compound, (C(4)H(7)N(2))(2)[CoCl(4)], consists of two 2-methyl­imidazolium cations and one tetra­hedral [CoCl(4)](2−) anion. The anions and cations inter­act through N—H⋯Cl hydrogen bonds to define layers with a stacking direction along [100]. Besides van der Waals forces, weak C—H⋯Cl inter­actions between these layers stabilize the crystal packing.
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spelling pubmed-45553862015-09-22 Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II) Diop, Mouhamadou Birame Diop, Libasse Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications The asymmetric unit of the title compound, (C(4)H(7)N(2))(2)[CoCl(4)], consists of two 2-methyl­imidazolium cations and one tetra­hedral [CoCl(4)](2−) anion. The anions and cations inter­act through N—H⋯Cl hydrogen bonds to define layers with a stacking direction along [100]. Besides van der Waals forces, weak C—H⋯Cl inter­actions between these layers stabilize the crystal packing. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555386/ /pubmed/26396849 http://dx.doi.org/10.1107/S2056989015014127 Text en © Diop et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Diop, Mouhamadou Birame
Diop, Libasse
Maris, Thierry
Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title_full Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title_fullStr Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title_full_unstemmed Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title_short Crystal structure of bis­(2-methyl-1H-imidazol-3-ium) tetra­chlorido­cobaltate(II)
title_sort crystal structure of bis­(2-methyl-1h-imidazol-3-ium) tetra­chlorido­cobaltate(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555386/
https://www.ncbi.nlm.nih.gov/pubmed/26396849
http://dx.doi.org/10.1107/S2056989015014127
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