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Crystal structure of 6,7-di­chloro-4-oxo-4H-chromene-3-carbaldehyde

In the title compound, C(10)H(4)Cl(2)O(3), a dichlorinated 3-formyl­chromone, the non-H atoms of the 4H-chromene ring are essentially coplanar (r.m.s. = 0.0188 Å), with the largest deviation from the least-squares plane [0.043 (2) Å] being for the pyran C=O C atom. The α,β-unsaturated carbonyl O ato...

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Detalles Bibliográficos
Autor principal: Ishikawa, Yoshinobu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555387/
https://www.ncbi.nlm.nih.gov/pubmed/26396886
http://dx.doi.org/10.1107/S2056989015014644
Descripción
Sumario:In the title compound, C(10)H(4)Cl(2)O(3), a dichlorinated 3-formyl­chromone, the non-H atoms of the 4H-chromene ring are essentially coplanar (r.m.s. = 0.0188 Å), with the largest deviation from the least-squares plane [0.043 (2) Å] being for the pyran C=O C atom. The α,β-unsaturated carbonyl O atom deviates from the least-square plane by 0.124 (2) Å. The dihedral angle between the chromone and formyl least-square planes is 6.76 (3)°. In the crystal, mol­ecules are linked through C—H⋯O hydrogen bonds between the translation-symmetry and inversion-symmetry equivalents to form tetrads, which are further assembled by stacking inter­actions [centroid–centroid distance between the benzene rings = 3.769 (2) Å]. van der Waals contacts are found between the Cl atoms at the 6-position and the Cl atoms at 7-position of the glide-reflection-symmetry equivalents [Cl⋯Cl = 3.4785 (16) Å, C—Cl⋯Cl = 160.23 (7)° and Cl⋯Cl—C = 122.59 (7)°].