Crystal structure of 5-benzoyl-2,4-di­phenyl-4,5-di­hydro­furan-3-carbo­nitrile

In the title compound, C(24)H(17)NO(2), the carbonyl O atom of the benzoyl group is cis with respect to the furanyl O atom, and the associated O—C—C—O torsion angle is 4.62 (19)°. The puckering of the dihydro­furan ring is close to twisted ((4) T (5)), with parameters Q = 0.1856 (16) Å and φ = 313.5...

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Detalles Bibliográficos
Autores principales: Rajni Swamy, V., Krishnakumar, R.V., Sivakumar, S., Srinivasan, N., Ranjith Kumar, R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555400/
https://www.ncbi.nlm.nih.gov/pubmed/26396892
http://dx.doi.org/10.1107/S2056989015014887
Descripción
Sumario:In the title compound, C(24)H(17)NO(2), the carbonyl O atom of the benzoyl group is cis with respect to the furanyl O atom, and the associated O—C—C—O torsion angle is 4.62 (19)°. The puckering of the dihydro­furan ring is close to twisted ((4) T (5)), with parameters Q = 0.1856 (16) Å and φ = 313.5 (5)°. Mol­ecules are inter­connected via a C—H⋯N and a C—H⋯O hydrogen bond, leading to layers parallel to the (200) plane and characterized by R (4) (4)(28) and R (4) (4)(36) graph-set motifs. The furan O atom does not participate in inter­molecular hydrogen bonding. The crystal lattice encompasses a solvent-accessible void of 24.7 (8) Å(3).

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