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Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione

In the acridinedione moiety of the title compound, C(32)H(37)NO(4), the central di­hydro­pyridine ring adopts a flattened-boat conformation, with the N atom and the methine C atom displaced from the mean plane of the other four atoms by 0.0513 (14) and 0.1828 (18) Å, respectively. The two cyclo­hexe...

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Autores principales: Sureshbabu, N., Sughanya, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555413/
https://www.ncbi.nlm.nih.gov/pubmed/26396906
http://dx.doi.org/10.1107/S2056989015014966
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author Sureshbabu, N.
Sughanya, V.
author_facet Sureshbabu, N.
Sughanya, V.
author_sort Sureshbabu, N.
collection PubMed
description In the acridinedione moiety of the title compound, C(32)H(37)NO(4), the central di­hydro­pyridine ring adopts a flattened-boat conformation, with the N atom and the methine C atom displaced from the mean plane of the other four atoms by 0.0513 (14) and 0.1828 (18) Å, respectively. The two cyclo­hexenone rings adopt envelope conformations, with the tetra­subsituted C atoms as the flap atoms. The 3,4-di­meth­oxy­­benzene and benzyl rings are almost normal to the di­hydro­pyridine mean plane, with dihedral angles of 89.47 (9) and 82.90 (11)°, respectively. In the crystal, mol­ecules are linked via a pair of C—H⋯O hydrogen bonds, forming inversion dimers, which are, in turn, linked by C—H⋯O hydrogen bonds, forming slabs lying parallel to (001).
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spelling pubmed-45554132015-09-22 Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione Sureshbabu, N. Sughanya, V. Acta Crystallogr E Crystallogr Commun Data Reports In the acridinedione moiety of the title compound, C(32)H(37)NO(4), the central di­hydro­pyridine ring adopts a flattened-boat conformation, with the N atom and the methine C atom displaced from the mean plane of the other four atoms by 0.0513 (14) and 0.1828 (18) Å, respectively. The two cyclo­hexenone rings adopt envelope conformations, with the tetra­subsituted C atoms as the flap atoms. The 3,4-di­meth­oxy­­benzene and benzyl rings are almost normal to the di­hydro­pyridine mean plane, with dihedral angles of 89.47 (9) and 82.90 (11)°, respectively. In the crystal, mol­ecules are linked via a pair of C—H⋯O hydrogen bonds, forming inversion dimers, which are, in turn, linked by C—H⋯O hydrogen bonds, forming slabs lying parallel to (001). International Union of Crystallography 2015-08-26 /pmc/articles/PMC4555413/ /pubmed/26396906 http://dx.doi.org/10.1107/S2056989015014966 Text en © Sureshbabu and Sughanya 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sureshbabu, N.
Sughanya, V.
Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title_full Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title_fullStr Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title_full_unstemmed Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title_short Crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2H,5H)-dione
title_sort crystal structure of 10-benzyl-9-(3,4-di­meth­oxy­phen­yl)-3,3,6,6-tetra­methyl-3,4,6,7,9,10-hexa­hydro­acridine-1,8(2h,5h)-dione
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555413/
https://www.ncbi.nlm.nih.gov/pubmed/26396906
http://dx.doi.org/10.1107/S2056989015014966
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