Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)

The mol­ecular structure of the title compound, [HgCl(2)(C(3)H(8)N(2)S)(2)], has point group symmetry 2, with the twofold rotation axis passing through the Hg(II) atom. The latter is coordinated by two Cl atoms and two N,N′-di­methyl­thio­urea (Dmtu) ligands through their S atoms, defining a distort...

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Autores principales: Shaheen, Muhammad Ashraf, Munawar, Aisha, Sadaf, Haseeba, Tahir, Muhammad Nawaz, Isab, Anvarhusein A., Ahmad, Saeed
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555414/
https://www.ncbi.nlm.nih.gov/pubmed/26396848
http://dx.doi.org/10.1107/S2056989015015406
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author Shaheen, Muhammad Ashraf
Munawar, Aisha
Sadaf, Haseeba
Tahir, Muhammad Nawaz
Isab, Anvarhusein A.
Ahmad, Saeed
author_facet Shaheen, Muhammad Ashraf
Munawar, Aisha
Sadaf, Haseeba
Tahir, Muhammad Nawaz
Isab, Anvarhusein A.
Ahmad, Saeed
author_sort Shaheen, Muhammad Ashraf
collection PubMed
description The mol­ecular structure of the title compound, [HgCl(2)(C(3)H(8)N(2)S)(2)], has point group symmetry 2, with the twofold rotation axis passing through the Hg(II) atom. The latter is coordinated by two Cl atoms and two N,N′-di­methyl­thio­urea (Dmtu) ligands through their S atoms, defining a distorted tetra­hedral coordination sphere with bond angles in the range 102.47 (4)–118.32 (4)°. Intra- and inter­molecular hydrogen bonds of the type N—H⋯Cl with S(6) and R (2) (2)(12) ring motifs are present. The inter­molecular contacts make up polymeric chains extending parallel to [101].
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spelling pubmed-45554142015-09-22 Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II) Shaheen, Muhammad Ashraf Munawar, Aisha Sadaf, Haseeba Tahir, Muhammad Nawaz Isab, Anvarhusein A. Ahmad, Saeed Acta Crystallogr E Crystallogr Commun Research Communications The mol­ecular structure of the title compound, [HgCl(2)(C(3)H(8)N(2)S)(2)], has point group symmetry 2, with the twofold rotation axis passing through the Hg(II) atom. The latter is coordinated by two Cl atoms and two N,N′-di­methyl­thio­urea (Dmtu) ligands through their S atoms, defining a distorted tetra­hedral coordination sphere with bond angles in the range 102.47 (4)–118.32 (4)°. Intra- and inter­molecular hydrogen bonds of the type N—H⋯Cl with S(6) and R (2) (2)(12) ring motifs are present. The inter­molecular contacts make up polymeric chains extending parallel to [101]. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555414/ /pubmed/26396848 http://dx.doi.org/10.1107/S2056989015015406 Text en © Shaheen et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Shaheen, Muhammad Ashraf
Munawar, Aisha
Sadaf, Haseeba
Tahir, Muhammad Nawaz
Isab, Anvarhusein A.
Ahmad, Saeed
Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title_full Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title_fullStr Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title_full_unstemmed Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title_short Crystal structure of di­chlorido­bis­(N,N′-di­methyl­thio­urea-κS)mercury(II)
title_sort crystal structure of di­chlorido­bis­(n,n′-di­methyl­thio­urea-κs)mercury(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555414/
https://www.ncbi.nlm.nih.gov/pubmed/26396848
http://dx.doi.org/10.1107/S2056989015015406
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