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Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)

In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzo­thia­zolphenolate ligands, forming a distorted tetra­hedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzo­thia­z...

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Detalles Bibliográficos
Autores principales: Kim, Namhun, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/
https://www.ncbi.nlm.nih.gov/pubmed/26396872
http://dx.doi.org/10.1107/S2056989015015303
Descripción
Sumario:In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzo­thia­zolphenolate ligands, forming a distorted tetra­hedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzo­thia­zole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and inter­molecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π inter­actions between aromatic and thia­zole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the mol­ecules into a two-dimensional supra­molecular network along the bc plane.