Cargando…
Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2) N,O]copper(II)
In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzothiaz...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/ https://www.ncbi.nlm.nih.gov/pubmed/26396872 http://dx.doi.org/10.1107/S2056989015015303 |
Sumario: | In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzothiazole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and intermolecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π interactions between aromatic and thiazole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the molecules into a two-dimensional supramolecular network along the bc plane. |
---|