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Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2) N,O]copper(II)
In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzothiaz...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2015
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/ https://www.ncbi.nlm.nih.gov/pubmed/26396872 http://dx.doi.org/10.1107/S2056989015015303 |
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author | Kim, Namhun Kang, Sung Kwon |
author_facet | Kim, Namhun Kang, Sung Kwon |
author_sort | Kim, Namhun |
collection | PubMed |
description | In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzothiazole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and intermolecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π interactions between aromatic and thiazole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the molecules into a two-dimensional supramolecular network along the bc plane. |
format | Online Article Text |
id | pubmed-4555420 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45554202015-09-22 Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2) N,O]copper(II) Kim, Namhun Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzothiazolphenolate ligands, forming a distorted tetrahedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzothiazole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and intermolecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π interactions between aromatic and thiazole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the molecules into a two-dimensional supramolecular network along the bc plane. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555420/ /pubmed/26396872 http://dx.doi.org/10.1107/S2056989015015303 Text en © Kim and Kang 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Kim, Namhun Kang, Sung Kwon Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2) N,O]copper(II) |
title | Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
N,O]copper(II) |
title_full | Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
N,O]copper(II) |
title_fullStr | Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
N,O]copper(II) |
title_full_unstemmed | Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
N,O]copper(II) |
title_short | Crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
N,O]copper(II) |
title_sort | crystal structure of bis[2-(benzothiazol-2-yl)phenolato-κ(2)
n,o]copper(ii) |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/ https://www.ncbi.nlm.nih.gov/pubmed/26396872 http://dx.doi.org/10.1107/S2056989015015303 |
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