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Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)

In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzo­thia­zolphenolate ligands, forming a distorted tetra­hedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzo­thia­z...

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Detalles Bibliográficos
Autores principales: Kim, Namhun, Kang, Sung Kwon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/
https://www.ncbi.nlm.nih.gov/pubmed/26396872
http://dx.doi.org/10.1107/S2056989015015303
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author Kim, Namhun
Kang, Sung Kwon
author_facet Kim, Namhun
Kang, Sung Kwon
author_sort Kim, Namhun
collection PubMed
description In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzo­thia­zolphenolate ligands, forming a distorted tetra­hedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzo­thia­zole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and inter­molecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π inter­actions between aromatic and thia­zole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the mol­ecules into a two-dimensional supra­molecular network along the bc plane.
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spelling pubmed-45554202015-09-22 Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II) Kim, Namhun Kang, Sung Kwon Acta Crystallogr E Crystallogr Commun Data Reports In the title complex, [Cu(C(13)H(8)NOS)(2)], the Cu(II) atom is coordinated by two N atoms and two O atoms from two bidentate benzo­thia­zolphenolate ligands, forming a distorted tetra­hedral geometry [dihedral angle between two N—Cu—O planes: 45.1 (2)°]. The dihedral angles between the benzo­thia­zole ring systems and the phenol rings are 4.1 (4) and 5.8 (4)°, indicating an almost planar geometry. Weak intra- and inter­molecular C—H⋯O hydrogen bonds are observed. In the crystal, weak π–π inter­actions between aromatic and thia­zole rings [centroid–centroid distances = 3.626 (3) and 3.873 (3) Å] link the mol­ecules into a two-dimensional supra­molecular network along the bc plane. International Union of Crystallography 2015-08-22 /pmc/articles/PMC4555420/ /pubmed/26396872 http://dx.doi.org/10.1107/S2056989015015303 Text en © Kim and Kang 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kim, Namhun
Kang, Sung Kwon
Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title_full Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title_fullStr Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title_full_unstemmed Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title_short Crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) N,O]copper(II)
title_sort crystal structure of bis­[2-(benzo­thia­zol-2-yl)phenolato-κ(2) n,o]copper(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555420/
https://www.ncbi.nlm.nih.gov/pubmed/26396872
http://dx.doi.org/10.1107/S2056989015015303
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