Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide

The title compound, C(27)H(26.82)BBr(2.18)N(+)·Br(3) (−), is a cationic tri­aryl­borane isolated as its tribromide salt. The aryl substituents include a protonated 8-quinolyl group and two 3-bromo­mesityl groups. The mol­ecule was prepared on combination of 3:1 Br(2) and dimesit­yl(quinolin-8-yl)bor...

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Detalles Bibliográficos
Autores principales: Son, Jungho, Tamang, Sem Raj, Hoefelmeyer, James D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555423/
https://www.ncbi.nlm.nih.gov/pubmed/26396861
http://dx.doi.org/10.1107/S2056989015015467
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author Son, Jungho
Tamang, Sem Raj
Hoefelmeyer, James D.
author_facet Son, Jungho
Tamang, Sem Raj
Hoefelmeyer, James D.
author_sort Son, Jungho
collection PubMed
description The title compound, C(27)H(26.82)BBr(2.18)N(+)·Br(3) (−), is a cationic tri­aryl­borane isolated as its tribromide salt. The aryl substituents include a protonated 8-quinolyl group and two 3-bromo­mesityl groups. The mol­ecule was prepared on combination of 3:1 Br(2) and dimesit­yl(quinolin-8-yl)borane in hexa­nes. The refinement of the structure indicated a degree of ‘over-bromination’ (beyond two bromine atoms) for the cation. There are two tribromide ions in the asymmetric unit, both completed by crystallographic inversion symmetry.
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spelling pubmed-45554232015-09-22 Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide Son, Jungho Tamang, Sem Raj Hoefelmeyer, James D. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(27)H(26.82)BBr(2.18)N(+)·Br(3) (−), is a cationic tri­aryl­borane isolated as its tribromide salt. The aryl substituents include a protonated 8-quinolyl group and two 3-bromo­mesityl groups. The mol­ecule was prepared on combination of 3:1 Br(2) and dimesit­yl(quinolin-8-yl)borane in hexa­nes. The refinement of the structure indicated a degree of ‘over-bromination’ (beyond two bromine atoms) for the cation. There are two tribromide ions in the asymmetric unit, both completed by crystallographic inversion symmetry. International Union of Crystallography 2015-08-29 /pmc/articles/PMC4555423/ /pubmed/26396861 http://dx.doi.org/10.1107/S2056989015015467 Text en © Son et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Son, Jungho
Tamang, Sem Raj
Hoefelmeyer, James D.
Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title_full Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title_fullStr Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title_full_unstemmed Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title_short Crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(III) tribromide
title_sort crystal structure of bis­(3-bromo­mesit­yl)(quino­lin-1-ium-8-yl)boron(iii) tribromide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555423/
https://www.ncbi.nlm.nih.gov/pubmed/26396861
http://dx.doi.org/10.1107/S2056989015015467
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AT tamangsemraj crystalstructureofbis3bromomesitylquinolin1ium8ylboroniiitribromide
AT hoefelmeyerjamesd crystalstructureofbis3bromomesitylquinolin1ium8ylboroniiitribromide

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