Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]

The binuclear title complex, [Cu(2)I(2)(C(26)H(24)P(2))(2)(C(5)H(12)N(2)S)(2)], lies about an inversion centre. The Cu(I) atom displays a distorted tetra­hedral coordination geometry defined by one S atom of an N,N′-di­ethyl­thio­urea ligand, two P atoms derived from two bridging 1,2-bis­(di­phenyl­...

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Autores principales: Khongsichan, Ladawan, Nimthong-Roldán, Arunpatcha, Pakawatchai, Chaveng, Wongnawa, Sumpun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555430/
https://www.ncbi.nlm.nih.gov/pubmed/26396862
http://dx.doi.org/10.1107/S2056989015014176
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author Khongsichan, Ladawan
Nimthong-Roldán, Arunpatcha
Pakawatchai, Chaveng
Wongnawa, Sumpun
author_facet Khongsichan, Ladawan
Nimthong-Roldán, Arunpatcha
Pakawatchai, Chaveng
Wongnawa, Sumpun
author_sort Khongsichan, Ladawan
collection PubMed
description The binuclear title complex, [Cu(2)I(2)(C(26)H(24)P(2))(2)(C(5)H(12)N(2)S)(2)], lies about an inversion centre. The Cu(I) atom displays a distorted tetra­hedral coordination geometry defined by one S atom of an N,N′-di­ethyl­thio­urea ligand, two P atoms derived from two bridging 1,2-bis­(di­phenyl­phosphan­yl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu(2)P(4)C(4) ring. An intra­molecular N—H⋯I hydrogen bond is noted. In the crystal, N—H⋯I hydrogen bonds link complex mol­ecules into layers parallel to (-101).
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spelling pubmed-45554302015-09-22 Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)] Khongsichan, Ladawan Nimthong-Roldán, Arunpatcha Pakawatchai, Chaveng Wongnawa, Sumpun Acta Crystallogr E Crystallogr Commun Data Reports The binuclear title complex, [Cu(2)I(2)(C(26)H(24)P(2))(2)(C(5)H(12)N(2)S)(2)], lies about an inversion centre. The Cu(I) atom displays a distorted tetra­hedral coordination geometry defined by one S atom of an N,N′-di­ethyl­thio­urea ligand, two P atoms derived from two bridging 1,2-bis­(di­phenyl­phosphan­yl)ethane (dppe) ligands and one iodide ion. The dppe ligand bridges two symmetry-related Cu(I) ions, forming a 10-membered Cu(2)P(4)C(4) ring. An intra­molecular N—H⋯I hydrogen bond is noted. In the crystal, N—H⋯I hydrogen bonds link complex mol­ecules into layers parallel to (-101). International Union of Crystallography 2015-08-06 /pmc/articles/PMC4555430/ /pubmed/26396862 http://dx.doi.org/10.1107/S2056989015014176 Text en © Khongsichan et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Khongsichan, Ladawan
Nimthong-Roldán, Arunpatcha
Pakawatchai, Chaveng
Wongnawa, Sumpun
Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title_full Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title_fullStr Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title_full_unstemmed Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title_short Crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) P:P′]bis[(N,N′-di­ethyl­thio­urea-κS)iodidocopper(I)]
title_sort crystal structure of bis­[μ-1,2-bis­(di­phenyl­phosphan­yl)ethane-κ(2) p:p′]bis[(n,n′-di­ethyl­thio­urea-κs)iodidocopper(i)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555430/
https://www.ncbi.nlm.nih.gov/pubmed/26396862
http://dx.doi.org/10.1107/S2056989015014176
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