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Crystal structure of 2,2′-bis[(2-chlorobenzyl)oxy]-1,1′-binaphthalene
In the title binaphthyl compound, C(34)H(24)Cl(2)O(2), the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chlorophenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihed...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555433/ https://www.ncbi.nlm.nih.gov/pubmed/26396878 http://dx.doi.org/10.1107/S2056989015014322 |
Sumario: | In the title binaphthyl compound, C(34)H(24)Cl(2)O(2), the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chlorophenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chlorophenyl rings is 27.66 (16)°. In the crystal, C—H⋯O hydrogen bonds link molecules into chains propagating along [1-10]. The chains are linked by C—H⋯π interactions, forming a three-dimensional framework. |
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