Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene

In the title binaphthyl compound, C(34)H(24)Cl(2)O(2), the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro­phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihed...

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Autores principales: Raja, Rajamani, Jayanthi, Mani, Rajakumar, Perumal, SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555433/
https://www.ncbi.nlm.nih.gov/pubmed/26396878
http://dx.doi.org/10.1107/S2056989015014322
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author Raja, Rajamani
Jayanthi, Mani
Rajakumar, Perumal
SubbiahPandi, A.
author_facet Raja, Rajamani
Jayanthi, Mani
Rajakumar, Perumal
SubbiahPandi, A.
author_sort Raja, Rajamani
collection PubMed
description In the title binaphthyl compound, C(34)H(24)Cl(2)O(2), the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro­phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro­phenyl rings is 27.66 (16)°. In the crystal, C—H⋯O hydrogen bonds link mol­ecules into chains propagating along [1-10]. The chains are linked by C—H⋯π inter­actions, forming a three-dimensional framework.
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spelling pubmed-45554332015-09-22 Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene Raja, Rajamani Jayanthi, Mani Rajakumar, Perumal SubbiahPandi, A. Acta Crystallogr E Crystallogr Commun Data Reports In the title binaphthyl compound, C(34)H(24)Cl(2)O(2), the dihedral angle between the two naphthyl ring systems (r.m.s. deviations = 0.016 and 0.035 Å) is 76.33 (8)°. The chloro­phenyl rings make dihedral angles of 58.15 (12) and 76.21 (13)° with the naphthyl ring to which they are linked. The dihedral angle between the planes of the two chloro­phenyl rings is 27.66 (16)°. In the crystal, C—H⋯O hydrogen bonds link mol­ecules into chains propagating along [1-10]. The chains are linked by C—H⋯π inter­actions, forming a three-dimensional framework. International Union of Crystallography 2015-08-06 /pmc/articles/PMC4555433/ /pubmed/26396878 http://dx.doi.org/10.1107/S2056989015014322 Text en © Raja et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Raja, Rajamani
Jayanthi, Mani
Rajakumar, Perumal
SubbiahPandi, A.
Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title_full Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title_fullStr Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title_full_unstemmed Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title_short Crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
title_sort crystal structure of 2,2′-bis­[(2-chloro­benz­yl)­oxy]-1,1′-bi­naphthalene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555433/
https://www.ncbi.nlm.nih.gov/pubmed/26396878
http://dx.doi.org/10.1107/S2056989015014322
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