Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate

The title mol­ecular salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), crystallized with two independent cations and anions in the asymmetric unit. The ethanaminium side chains of the cations exhibit anti conformations [C—C—C—N torsion angles = 176.5 (3) and −179.4 (3)°]. In the crystal, N—H⋯O and C—H⋯O hydroge...

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Autores principales: Sowmya, N. Swarna, Sampathkrishnan, S., Akilan, R., Chakkaravarthi, G., Kumar, R. Mohan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555434/
https://www.ncbi.nlm.nih.gov/pubmed/26396880
http://dx.doi.org/10.1107/S2056989015014292
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author Sowmya, N. Swarna
Sampathkrishnan, S.
Akilan, R.
Chakkaravarthi, G.
Kumar, R. Mohan
author_facet Sowmya, N. Swarna
Sampathkrishnan, S.
Akilan, R.
Chakkaravarthi, G.
Kumar, R. Mohan
author_sort Sowmya, N. Swarna
collection PubMed
description The title mol­ecular salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), crystallized with two independent cations and anions in the asymmetric unit. The ethanaminium side chains of the cations exhibit anti conformations [C—C—C—N torsion angles = 176.5 (3) and −179.4 (3)°]. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds connect adjacent anions and cations, and , O—H⋯O hydrogen bonds connect adjacent anions, generating sheets parallel to (001).
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spelling pubmed-45554342015-09-22 Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate Sowmya, N. Swarna Sampathkrishnan, S. Akilan, R. Chakkaravarthi, G. Kumar, R. Mohan Acta Crystallogr E Crystallogr Commun Data Reports The title mol­ecular salt, C(8)H(12)N(+)·C(4)H(3)O(4) (−), crystallized with two independent cations and anions in the asymmetric unit. The ethanaminium side chains of the cations exhibit anti conformations [C—C—C—N torsion angles = 176.5 (3) and −179.4 (3)°]. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds connect adjacent anions and cations, and , O—H⋯O hydrogen bonds connect adjacent anions, generating sheets parallel to (001). International Union of Crystallography 2015-08-06 /pmc/articles/PMC4555434/ /pubmed/26396880 http://dx.doi.org/10.1107/S2056989015014292 Text en © Sowmya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Sowmya, N. Swarna
Sampathkrishnan, S.
Akilan, R.
Chakkaravarthi, G.
Kumar, R. Mohan
Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title_full Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title_fullStr Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title_full_unstemmed Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title_short Crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
title_sort crystal structure of 2-phenyl­ethanaminium 3-carb­oxy­prop-2-enoate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555434/
https://www.ncbi.nlm.nih.gov/pubmed/26396880
http://dx.doi.org/10.1107/S2056989015014292
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