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Crystal structure of 2-aminopyridinium 6-chloronicotinate
In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further v...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555436/ https://www.ncbi.nlm.nih.gov/pubmed/26396888 http://dx.doi.org/10.1107/S2056989015014796 |
Sumario: | In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further via N—H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C—H⋯N and C—H⋯O hydrogen bonds, together with weak π–π interactions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) Å, connect the chains, forming a two-dimensional network parallel to (100). |
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