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Crystal structure of 2-amino­pyridinium 6-chloro­nicotinate

In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-amino­pyri­din­ium cation inter­acts with the carboxyl­ate group of the 6-chloro­nicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further v...

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Detalles Bibliográficos
Autores principales: Jasmine, N. Jeeva, Rajam, A., Muthiah, P. Thomas, Stanley, N., Razak, I. Abdul, Rosli, M. Mustaqim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555436/
https://www.ncbi.nlm.nih.gov/pubmed/26396888
http://dx.doi.org/10.1107/S2056989015014796
Descripción
Sumario:In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-amino­pyri­din­ium cation inter­acts with the carboxyl­ate group of the 6-chloro­nicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further via N—H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C—H⋯N and C—H⋯O hydrogen bonds, together with weak π–π inter­actions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) Å, connect the chains, forming a two-dimensional network parallel to (100).