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Crystal structure of 2-aminopyridinium 6-chloronicotinate
In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further v...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555436/ https://www.ncbi.nlm.nih.gov/pubmed/26396888 http://dx.doi.org/10.1107/S2056989015014796 |
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author | Jasmine, N. Jeeva Rajam, A. Muthiah, P. Thomas Stanley, N. Razak, I. Abdul Rosli, M. Mustaqim |
author_facet | Jasmine, N. Jeeva Rajam, A. Muthiah, P. Thomas Stanley, N. Razak, I. Abdul Rosli, M. Mustaqim |
author_sort | Jasmine, N. Jeeva |
collection | PubMed |
description | In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further via N—H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C—H⋯N and C—H⋯O hydrogen bonds, together with weak π–π interactions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) Å, connect the chains, forming a two-dimensional network parallel to (100). |
format | Online Article Text |
id | pubmed-4555436 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45554362015-09-22 Crystal structure of 2-aminopyridinium 6-chloronicotinate Jasmine, N. Jeeva Rajam, A. Muthiah, P. Thomas Stanley, N. Razak, I. Abdul Rosli, M. Mustaqim Acta Crystallogr E Crystallogr Commun Data Reports In the title salt, C(5)H(7)N(+)·C(6)H(3)ClNO(−), the 2-aminopyridinium cation interacts with the carboxylate group of the 6-chloronicotinate anion through a pair of independent N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. In the crystal, these dimeric units are connected further via N—H⋯O hydrogen bonds, forming chains along [001]. In addition, weak C—H⋯N and C—H⋯O hydrogen bonds, together with weak π–π interactions, with centroid–centroid distances of 3.6560 (5) and 3.6295 (5) Å, connect the chains, forming a two-dimensional network parallel to (100). International Union of Crystallography 2015-08-12 /pmc/articles/PMC4555436/ /pubmed/26396888 http://dx.doi.org/10.1107/S2056989015014796 Text en © Jasmine et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Jasmine, N. Jeeva Rajam, A. Muthiah, P. Thomas Stanley, N. Razak, I. Abdul Rosli, M. Mustaqim Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title_full | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title_fullStr | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title_full_unstemmed | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title_short | Crystal structure of 2-aminopyridinium 6-chloronicotinate |
title_sort | crystal structure of 2-aminopyridinium 6-chloronicotinate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555436/ https://www.ncbi.nlm.nih.gov/pubmed/26396888 http://dx.doi.org/10.1107/S2056989015014796 |
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