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Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone
In the title β-thiocarbonyl compound, C(16)H(16)O(3)S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the methoxy group is coplanar with the benzene rin...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555440/ https://www.ncbi.nlm.nih.gov/pubmed/26396889 http://dx.doi.org/10.1107/S2056989015014565 |
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author | Caracelli, Ignez Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. |
author_facet | Caracelli, Ignez Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. |
author_sort | Caracelli, Ignez |
collection | PubMed |
description | In the title β-thiocarbonyl compound, C(16)H(16)O(3)S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the methoxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H⋯O(carbonyl) interactions that lead to a supramolecular chain with a zigzag topology along the c axis. Chains pack with no specific intermolecular interactions between them. |
format | Online Article Text |
id | pubmed-4555440 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45554402015-09-22 Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone Caracelli, Ignez Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Data Reports In the title β-thiocarbonyl compound, C(16)H(16)O(3)S, the adjacent methoxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the methoxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H⋯O(carbonyl) interactions that lead to a supramolecular chain with a zigzag topology along the c axis. Chains pack with no specific intermolecular interactions between them. International Union of Crystallography 2015-08-15 /pmc/articles/PMC4555440/ /pubmed/26396889 http://dx.doi.org/10.1107/S2056989015014565 Text en © Caracelli et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Caracelli, Ignez Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title | Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title_full | Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title_fullStr | Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title_full_unstemmed | Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title_short | Crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
title_sort | crystal structure of 2-methoxy-2-[(4-methoxyphenyl)sulfanyl]-1-phenylethanone |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555440/ https://www.ncbi.nlm.nih.gov/pubmed/26396889 http://dx.doi.org/10.1107/S2056989015014565 |
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