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Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone

In the title β-thio­carbonyl compound, C(16)H(16)O(3)S, the adjacent meth­oxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the meth­oxy group is coplanar with the benzene rin...

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Autores principales: Caracelli, Ignez, Olivato, Paulo R., Traesel, Henrique J., Valença, Jéssica, Rodrigues, Daniel N. S., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555440/
https://www.ncbi.nlm.nih.gov/pubmed/26396889
http://dx.doi.org/10.1107/S2056989015014565
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author Caracelli, Ignez
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
author_facet Caracelli, Ignez
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
author_sort Caracelli, Ignez
collection PubMed
description In the title β-thio­carbonyl compound, C(16)H(16)O(3)S, the adjacent meth­oxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the meth­oxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H⋯O(carbon­yl) inter­actions that lead to a supra­molecular chain with a zigzag topology along the c axis. Chains pack with no specific inter­molecular inter­actions between them.
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spelling pubmed-45554402015-09-22 Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone Caracelli, Ignez Olivato, Paulo R. Traesel, Henrique J. Valença, Jéssica Rodrigues, Daniel N. S. Tiekink, Edward R. T. Acta Crystallogr E Crystallogr Commun Data Reports In the title β-thio­carbonyl compound, C(16)H(16)O(3)S, the adjacent meth­oxy and carbonyl O atoms are synperiplanar [the O—C—C—O torsion angle is 19.8 (4)°] and are separated by 2.582 (3) Å. The dihedral angle between the rings is 40.11 (16)°, and the meth­oxy group is coplanar with the benzene ring to which it is connected [the C—C—O—C torsion angle is 179.1 (3)°]. The most notable feature of the crystal packing is the formation of methine and methyl C—H⋯O(carbon­yl) inter­actions that lead to a supra­molecular chain with a zigzag topology along the c axis. Chains pack with no specific inter­molecular inter­actions between them. International Union of Crystallography 2015-08-15 /pmc/articles/PMC4555440/ /pubmed/26396889 http://dx.doi.org/10.1107/S2056989015014565 Text en © Caracelli et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Caracelli, Ignez
Olivato, Paulo R.
Traesel, Henrique J.
Valença, Jéssica
Rodrigues, Daniel N. S.
Tiekink, Edward R. T.
Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title_full Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title_fullStr Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title_full_unstemmed Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title_short Crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
title_sort crystal structure of 2-meth­oxy-2-[(4-meth­oxy­phen­yl)sulfan­yl]-1-phenyl­ethanone
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4555440/
https://www.ncbi.nlm.nih.gov/pubmed/26396889
http://dx.doi.org/10.1107/S2056989015014565
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