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P–C-Activated Bimetallic Rhodium Xantphos Complexes: Formation and Catalytic Dehydrocoupling of Amine–Boranes**
{Rh(xantphos)}-based phosphido dimers form by P–C activation of xantphos (4,5-bis(diphenylphosphino)-9,9-dimethylxanthene) in the presence of amine–boranes. These dimers are active dehydrocoupling catalysts, forming polymeric [H(2)BNMeH](n) from H(3)B⋅NMeH(2) and dimeric [H(2)BNMe(2)](2) from H(3)B⋅...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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WILEY-VCH Verlag
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4557049/ https://www.ncbi.nlm.nih.gov/pubmed/26140498 http://dx.doi.org/10.1002/anie.201504073 |