All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**

1,3-Enynes containing allylic hydrogens cis to the alkyne function as three-carbon components in rhodium(III)-catalyzed, all-carbon [3+3] oxidative annulations to produce spirodialins. The proposed mechanism of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration.

Detalles Bibliográficos
Autores principales: Burns, David J, Best, Daniel, Wieczysty, Martin D, Lam, Hon Wai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2015
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4557058/
https://www.ncbi.nlm.nih.gov/pubmed/26224377
http://dx.doi.org/10.1002/anie.201503978
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author Burns, David J
Best, Daniel
Wieczysty, Martin D
Lam, Hon Wai
author_facet Burns, David J
Best, Daniel
Wieczysty, Martin D
Lam, Hon Wai
author_sort Burns, David J
collection PubMed
description 1,3-Enynes containing allylic hydrogens cis to the alkyne function as three-carbon components in rhodium(III)-catalyzed, all-carbon [3+3] oxidative annulations to produce spirodialins. The proposed mechanism of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration.
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spelling pubmed-45570582015-09-08 All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration** Burns, David J Best, Daniel Wieczysty, Martin D Lam, Hon Wai Angew Chem Int Ed Engl Communications 1,3-Enynes containing allylic hydrogens cis to the alkyne function as three-carbon components in rhodium(III)-catalyzed, all-carbon [3+3] oxidative annulations to produce spirodialins. The proposed mechanism of these reactions involves the alkenyl-to-allyl 1,4-rhodium(III) migration. WILEY-VCH Verlag 2015-08-17 2015-07-14 /pmc/articles/PMC4557058/ /pubmed/26224377 http://dx.doi.org/10.1002/anie.201503978 Text en © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. https://creativecommons.org/licenses/by/4.0/ © 2015 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Burns, David J
Best, Daniel
Wieczysty, Martin D
Lam, Hon Wai
All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title_full All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title_fullStr All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title_full_unstemmed All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title_short All-Carbon [3+3] Oxidative Annulations of 1,3-Enynes by Rhodium(III)-Catalyzed C–H Functionalization and 1,4-Migration**
title_sort all-carbon [3+3] oxidative annulations of 1,3-enynes by rhodium(iii)-catalyzed c–h functionalization and 1,4-migration**
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4557058/
https://www.ncbi.nlm.nih.gov/pubmed/26224377
http://dx.doi.org/10.1002/anie.201503978
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