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Proposal for universality in the viscosity of metallic liquids

The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (η(o)) to that at the glass transition temperature, T(g). We pr...

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Detalles Bibliográficos
Autores principales: Blodgett, M. E., Egami, T., Nussinov, Z., Kelton, K. F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4563367/
https://www.ncbi.nlm.nih.gov/pubmed/26350788
http://dx.doi.org/10.1038/srep13837
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author Blodgett, M. E.
Egami, T.
Nussinov, Z.
Kelton, K. F.
author_facet Blodgett, M. E.
Egami, T.
Nussinov, Z.
Kelton, K. F.
author_sort Blodgett, M. E.
collection PubMed
description The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (η(o)) to that at the glass transition temperature, T(g). We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/η(o)) as a function of T(A)/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature T(A) corresponds to the onset of cooperative motion and is strongly correlated with T(g), suggesting that the processes underlying the glass transition first appear in the high temperature liquid.
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spelling pubmed-45633672015-09-15 Proposal for universality in the viscosity of metallic liquids Blodgett, M. E. Egami, T. Nussinov, Z. Kelton, K. F. Sci Rep Article The range of magnitude of the liquid viscosity, η, as a function of temperature is one of the most impressive of any physical property, changing by approximately 17 orders of magnitude from its extrapolated value at infinite temperature (η(o)) to that at the glass transition temperature, T(g). We present experimental measurements of containerlessly processed metallic liquids that suggest that log(η/η(o)) as a function of T(A)/T is a potentially universal scaled curve. In stark contrast to previous approaches, the scaling requires only two fitting parameters, which are on average predictable. The temperature T(A) corresponds to the onset of cooperative motion and is strongly correlated with T(g), suggesting that the processes underlying the glass transition first appear in the high temperature liquid. Nature Publishing Group 2015-09-09 /pmc/articles/PMC4563367/ /pubmed/26350788 http://dx.doi.org/10.1038/srep13837 Text en Copyright © 2015, Macmillan Publishers Limited http://creativecommons.org/licenses/by/4.0/ This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
spellingShingle Article
Blodgett, M. E.
Egami, T.
Nussinov, Z.
Kelton, K. F.
Proposal for universality in the viscosity of metallic liquids
title Proposal for universality in the viscosity of metallic liquids
title_full Proposal for universality in the viscosity of metallic liquids
title_fullStr Proposal for universality in the viscosity of metallic liquids
title_full_unstemmed Proposal for universality in the viscosity of metallic liquids
title_short Proposal for universality in the viscosity of metallic liquids
title_sort proposal for universality in the viscosity of metallic liquids
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4563367/
https://www.ncbi.nlm.nih.gov/pubmed/26350788
http://dx.doi.org/10.1038/srep13837
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