Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates

[Image: see text] A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated...

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Autores principales: Sardzinski, Logan W., Wertjes, William C., Schnaith, Abigail M., Kalyani, Dipannita
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2015
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4565129/
https://www.ncbi.nlm.nih.gov/pubmed/25700128
http://dx.doi.org/10.1021/acs.orglett.5b00241
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author Sardzinski, Logan W.
Wertjes, William C.
Schnaith, Abigail M.
Kalyani, Dipannita
author_facet Sardzinski, Logan W.
Wertjes, William C.
Schnaith, Abigail M.
Kalyani, Dipannita
author_sort Sardzinski, Logan W.
collection PubMed
description [Image: see text] A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions.
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spelling pubmed-45651292016-02-20 Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates Sardzinski, Logan W. Wertjes, William C. Schnaith, Abigail M. Kalyani, Dipannita Org Lett [Image: see text] A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions. American Chemical Society 2015-02-20 2015-03-06 /pmc/articles/PMC4565129/ /pubmed/25700128 http://dx.doi.org/10.1021/acs.orglett.5b00241 Text en Copyright © 2015 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Sardzinski, Logan W.
Wertjes, William C.
Schnaith, Abigail M.
Kalyani, Dipannita
Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title_full Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title_fullStr Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title_full_unstemmed Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title_short Nickel-Catalyzed Decarboxylative Cross-Coupling of Perfluorobenzoates with Aryl Halides and Sulfonates
title_sort nickel-catalyzed decarboxylative cross-coupling of perfluorobenzoates with aryl halides and sulfonates
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4565129/
https://www.ncbi.nlm.nih.gov/pubmed/25700128
http://dx.doi.org/10.1021/acs.orglett.5b00241
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