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Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct
The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O—H⋯O h...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571351/ https://www.ncbi.nlm.nih.gov/pubmed/26396750 http://dx.doi.org/10.1107/S2056989015012621 |
Sumario: | The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O—H⋯O hydrogen bonds and adopt a syn–syn configuration, leading to a strand-like arrangement along [101]. The cyclohexylammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through intermolecular N—H⋯O interactions to both the succinate and the succinic acid components. This results in two-dimensional supramolecular layered structures lying parallel to (010). |
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