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Crystal structure of the bis­(cyclo­hexyl­ammonium) succinate succinic acid salt adduct

The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclo­hexyl­ammonium cations, one succcinate dianion and one neutral succinic acid mol­ecule. Succinate dianions and succinic acid mol­ecules are self-assembled head-to-tail through O—H⋯O h...

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Detalles Bibliográficos
Autores principales: Sarr, Modou, Diasse-Sarr, Aminata, Diop, Libasse, Plasseraud, Laurent, Cattey, Hélène
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571351/
https://www.ncbi.nlm.nih.gov/pubmed/26396750
http://dx.doi.org/10.1107/S2056989015012621
Descripción
Sumario:The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclo­hexyl­ammonium cations, one succcinate dianion and one neutral succinic acid mol­ecule. Succinate dianions and succinic acid mol­ecules are self-assembled head-to-tail through O—H⋯O hydrogen bonds and adopt a syn–syn configuration, leading to a strand-like arrangement along [101]. The cyclo­hexyl­ammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through inter­molecular N—H⋯O inter­actions to both the succinate and the succinic acid components. This results in two-dimensional supra­molecular layered structures lying parallel to (010).