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Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct
The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O—H⋯O h...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571351/ https://www.ncbi.nlm.nih.gov/pubmed/26396750 http://dx.doi.org/10.1107/S2056989015012621 |
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author | Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Plasseraud, Laurent Cattey, Hélène |
author_facet | Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Plasseraud, Laurent Cattey, Hélène |
author_sort | Sarr, Modou |
collection | PubMed |
description | The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O—H⋯O hydrogen bonds and adopt a syn–syn configuration, leading to a strand-like arrangement along [101]. The cyclohexylammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through intermolecular N—H⋯O interactions to both the succinate and the succinic acid components. This results in two-dimensional supramolecular layered structures lying parallel to (010). |
format | Online Article Text |
id | pubmed-4571351 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45713512015-09-22 Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Plasseraud, Laurent Cattey, Hélène Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title salt adduct, 2C(6)H(14)N(+)·C(4)H(4)O(4) (2−)·C(4)H(6)O(4), consists of two cyclohexylammonium cations, one succcinate dianion and one neutral succinic acid molecule. Succinate dianions and succinic acid molecules are self-assembled head-to-tail through O—H⋯O hydrogen bonds and adopt a syn–syn configuration, leading to a strand-like arrangement along [101]. The cyclohexylammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through intermolecular N—H⋯O interactions to both the succinate and the succinic acid components. This results in two-dimensional supramolecular layered structures lying parallel to (010). International Union of Crystallography 2015-07-08 /pmc/articles/PMC4571351/ /pubmed/26396750 http://dx.doi.org/10.1107/S2056989015012621 Text en © Sarr et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Sarr, Modou Diasse-Sarr, Aminata Diop, Libasse Plasseraud, Laurent Cattey, Hélène Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title | Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title_full | Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title_fullStr | Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title_full_unstemmed | Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title_short | Crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
title_sort | crystal structure of the bis(cyclohexylammonium) succinate succinic acid salt adduct |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571351/ https://www.ncbi.nlm.nih.gov/pubmed/26396750 http://dx.doi.org/10.1107/S2056989015012621 |
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