Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate

The Fe(III) ions in the hybrid title salt, (C(7)H(11)N(2))[Fe(C(2)O(4))(2)(H(2)O)(2)]·0.5H(2)O, show a distorted octa­hedral coordination environment, with four O atoms from two chelating oxalate dianions and two O atoms from two cis aqua ligands. The average Fe—O(oxalate) bond length [2.00 (2) Å] i...

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Autores principales: Djomo, Edith Dimitri, Capet, Frédéric, Nenwa, Justin, Bélombé, Michel M., Foulon, Michel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571360/
https://www.ncbi.nlm.nih.gov/pubmed/26396759
http://dx.doi.org/10.1107/S2056989015013213
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author Djomo, Edith Dimitri
Capet, Frédéric
Nenwa, Justin
Bélombé, Michel M.
Foulon, Michel
author_facet Djomo, Edith Dimitri
Capet, Frédéric
Nenwa, Justin
Bélombé, Michel M.
Foulon, Michel
author_sort Djomo, Edith Dimitri
collection PubMed
description The Fe(III) ions in the hybrid title salt, (C(7)H(11)N(2))[Fe(C(2)O(4))(2)(H(2)O)(2)]·0.5H(2)O, show a distorted octa­hedral coordination environment, with four O atoms from two chelating oxalate dianions and two O atoms from two cis aqua ligands. The average Fe—O(oxalate) bond length [2.00 (2) Å] is shorter than the average Fe—O(water) bond length [2.027 (19) Å]. The ionic components are connected via inter­molecular N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-45713602015-09-22 Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate Djomo, Edith Dimitri Capet, Frédéric Nenwa, Justin Bélombé, Michel M. Foulon, Michel Acta Crystallogr E Crystallogr Commun Research Communications The Fe(III) ions in the hybrid title salt, (C(7)H(11)N(2))[Fe(C(2)O(4))(2)(H(2)O)(2)]·0.5H(2)O, show a distorted octa­hedral coordination environment, with four O atoms from two chelating oxalate dianions and two O atoms from two cis aqua ligands. The average Fe—O(oxalate) bond length [2.00 (2) Å] is shorter than the average Fe—O(water) bond length [2.027 (19) Å]. The ionic components are connected via inter­molecular N—H⋯O and O—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2015-07-15 /pmc/articles/PMC4571360/ /pubmed/26396759 http://dx.doi.org/10.1107/S2056989015013213 Text en © Djomo et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Djomo, Edith Dimitri
Capet, Frédéric
Nenwa, Justin
Bélombé, Michel M.
Foulon, Michel
Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title_full Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title_fullStr Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title_full_unstemmed Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title_short Crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) O,O′)ferrate(III) hemihydrate
title_sort crystal structure of 4-(di­methyl­amino)­pyridinium cis-di­aqua­bis­(oxalato-κ(2) o,o′)ferrate(iii) hemihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571360/
https://www.ncbi.nlm.nih.gov/pubmed/26396759
http://dx.doi.org/10.1107/S2056989015013213
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