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Crystal structure of bis[μ-bis(diphenylphosphanyl)methane-κ(2) P:P′]digold(I) dichloride acetone monosolvate monohydrate

In the title complex salt, [Au(2){(C(6)H(5))(2)PCH(2)P(C(6)H(5))(2)}]Cl(2)·(CH(3))(2)C=O·H(2)O, the dication forms an eight-membered {—PCPAu}(2) ring with a transannular aurophilic interaction [Au⋯Au = 2.9743 (2) Å]. The ring approximates a flattened boat conformation, with the two methylene C ato...

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Detalles Bibliográficos
Autores principales:	Yeo, Chien Ing, Tan, Yee Seng, Tiekink, Edward R. T.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2015
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571361/ https://www.ncbi.nlm.nih.gov/pubmed/26396760 http://dx.doi.org/10.1107/S2056989015013341

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