Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate

The crystal structure of the title salt, [Fe(C(5)H(5))(C(8)H(13)N)](HC(2)O(4)), consists of discrete (ferrocenylmeth­yl)di­methyl­ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O—H⋯O hydrogen bond, forming linear chains running parallel to [100]. The cations...

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Autores principales: Ndiaye, Mamadou, Samb, Abdoulaye, Diop, Libasse, Maris, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571364/
https://www.ncbi.nlm.nih.gov/pubmed/26396763
http://dx.doi.org/10.1107/S205698901501333X
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author Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
author_facet Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
author_sort Ndiaye, Mamadou
collection PubMed
description The crystal structure of the title salt, [Fe(C(5)H(5))(C(8)H(13)N)](HC(2)O(4)), consists of discrete (ferrocenylmeth­yl)di­methyl­ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O—H⋯O hydrogen bond, forming linear chains running parallel to [100]. The cations are linked to the anions through bifurcated N—H⋯(O,O′) hydrogen bonds. Weak C—H⋯π inter­actions between neighbouring ferrocenyl moieties are also observed.
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spelling pubmed-45713642015-09-22 Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate Ndiaye, Mamadou Samb, Abdoulaye Diop, Libasse Maris, Thierry Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title salt, [Fe(C(5)H(5))(C(8)H(13)N)](HC(2)O(4)), consists of discrete (ferrocenylmeth­yl)di­methyl­ammonium cations and hydrogen oxalate anions. The anions are connected through a strong O—H⋯O hydrogen bond, forming linear chains running parallel to [100]. The cations are linked to the anions through bifurcated N—H⋯(O,O′) hydrogen bonds. Weak C—H⋯π inter­actions between neighbouring ferrocenyl moieties are also observed. International Union of Crystallography 2015-07-17 /pmc/articles/PMC4571364/ /pubmed/26396763 http://dx.doi.org/10.1107/S205698901501333X Text en © Ndiaye et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Ndiaye, Mamadou
Samb, Abdoulaye
Diop, Libasse
Maris, Thierry
Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title_full Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title_fullStr Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title_full_unstemmed Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title_short Crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
title_sort crystal structure of (ferrocenylmeth­yl)di­methyl­ammonium hydrogen oxalate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571364/
https://www.ncbi.nlm.nih.gov/pubmed/26396763
http://dx.doi.org/10.1107/S205698901501333X
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