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Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene

The title compound, [Fe(C(5)H(5))(C(27)H(24)OPS(2))], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to...

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Autores principales: Michelot, Audric, Sarda, Stéphanie, Daran, Jean-Claude, Deydier, Eric, Manoury, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571369/
https://www.ncbi.nlm.nih.gov/pubmed/26396768
http://dx.doi.org/10.1107/S2056989015013560
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author Michelot, Audric
Sarda, Stéphanie
Daran, Jean-Claude
Deydier, Eric
Manoury, Eric
author_facet Michelot, Audric
Sarda, Stéphanie
Daran, Jean-Claude
Deydier, Eric
Manoury, Eric
author_sort Michelot, Audric
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(27)H(24)OPS(2))], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to which they are attached. In the crystal, C—H⋯S hydrogen bonds link the mol­ecules into a ribbon running parallel to the (-110) plane. C—H⋯π inter­actions link the ribbons to form a three-dimensional network.
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spelling pubmed-45713692015-09-22 Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene Michelot, Audric Sarda, Stéphanie Daran, Jean-Claude Deydier, Eric Manoury, Eric Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Fe(C(5)H(5))(C(27)H(24)OPS(2))], is built up from a ferrocene moiety substituted in the 1- and 2-positions by {[4-(all­yloxy)phen­yl]sulfan­yl}methyl and di­phenyl­thio­phosphoryl groups, respectively. The two S atoms lie on opposite sides of the cyclo­penta­dienyl ring plane to which they are attached. In the crystal, C—H⋯S hydrogen bonds link the mol­ecules into a ribbon running parallel to the (-110) plane. C—H⋯π inter­actions link the ribbons to form a three-dimensional network. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571369/ /pubmed/26396768 http://dx.doi.org/10.1107/S2056989015013560 Text en © Michelot et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Michelot, Audric
Sarda, Stéphanie
Daran, Jean-Claude
Deydier, Eric
Manoury, Eric
Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title_full Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title_fullStr Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title_full_unstemmed Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title_short Crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
title_sort crystal structure of (±)-1-({[4-(all­yloxy)phen­yl]sulfan­yl}meth­yl)-2-(di­phenyl­thio­phosphor­yl)ferrocene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571369/
https://www.ncbi.nlm.nih.gov/pubmed/26396768
http://dx.doi.org/10.1107/S2056989015013560
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