Crystal structure of tetrakis­(acetyl­acetonato)di­chloridodi-μ(3)-methano­lato-tetra-μ(2)-methano­lato-tetra­iron(III)

The title complex, [Fe(4)(C(5)H(7)O(2))(4)(CH(3)O)(6)Cl(2)] or [Fe(4)(acac)(4)(μ(2)-OMe)(4)(μ(3)-OMe)(2)Cl(2)] (acac = acetyl­acetonate), crystallizes in the ortho­rhom­bic Pbca space group with one half of the mol­ecule per asymmetric unit, the other half being completed by inversion symmetry. The...

Descripción completa

Detalles Bibliográficos
Autores principales: Richers, Casseday P., Bertke, Jeffery A., Gray, Danielle L., Rauchfuss, Thomas B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571370/
https://www.ncbi.nlm.nih.gov/pubmed/26396769
http://dx.doi.org/10.1107/S2056989015013535
Descripción
Sumario:The title complex, [Fe(4)(C(5)H(7)O(2))(4)(CH(3)O)(6)Cl(2)] or [Fe(4)(acac)(4)(μ(2)-OMe)(4)(μ(3)-OMe)(2)Cl(2)] (acac = acetyl­acetonate), crystallizes in the ortho­rhom­bic Pbca space group with one half of the mol­ecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C—H⋯Cl inter­molecular inter­actions result in a two-dimensional layered structure parallel to the ac plane.

Ejemplares similares