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Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III)
The title complex, [Fe(4)(C(5)H(7)O(2))(4)(CH(3)O)(6)Cl(2)] or [Fe(4)(acac)(4)(μ(2)-OMe)(4)(μ(3)-OMe)(2)Cl(2)] (acac = acetylacetonate), crystallizes in the orthorhombic Pbca space group with one half of the molecule per asymmetric unit, the other half being completed by inversion symmetry. The...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2015
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571370/ https://www.ncbi.nlm.nih.gov/pubmed/26396769 http://dx.doi.org/10.1107/S2056989015013535 |
| _version_ | 1782390326717054976 |
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| author | Richers, Casseday P. Bertke, Jeffery A. Gray, Danielle L. Rauchfuss, Thomas B. |
| author_facet | Richers, Casseday P. Bertke, Jeffery A. Gray, Danielle L. Rauchfuss, Thomas B. |
| author_sort | Richers, Casseday P. |
| collection | PubMed |
| description | The title complex, [Fe(4)(C(5)H(7)O(2))(4)(CH(3)O)(6)Cl(2)] or [Fe(4)(acac)(4)(μ(2)-OMe)(4)(μ(3)-OMe)(2)Cl(2)] (acac = acetylacetonate), crystallizes in the orthorhombic Pbca space group with one half of the molecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C—H⋯Cl intermolecular interactions result in a two-dimensional layered structure parallel to the ac plane. |
| format | Online Article Text |
| id | pubmed-4571370 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2015 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-45713702015-09-22 Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) Richers, Casseday P. Bertke, Jeffery A. Gray, Danielle L. Rauchfuss, Thomas B. Acta Crystallogr E Crystallogr Commun Research Communications The title complex, [Fe(4)(C(5)H(7)O(2))(4)(CH(3)O)(6)Cl(2)] or [Fe(4)(acac)(4)(μ(2)-OMe)(4)(μ(3)-OMe)(2)Cl(2)] (acac = acetylacetonate), crystallizes in the orthorhombic Pbca space group with one half of the molecule per asymmetric unit, the other half being completed by inversion symmetry. The core structure consists of a face-sharing double pseudo-cubane entity with two opposite corners missing. Weak C—H⋯Cl intermolecular interactions result in a two-dimensional layered structure parallel to the ac plane. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571370/ /pubmed/26396769 http://dx.doi.org/10.1107/S2056989015013535 Text en © Richers et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Richers, Casseday P. Bertke, Jeffery A. Gray, Danielle L. Rauchfuss, Thomas B. Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title | Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title_full | Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title_fullStr | Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title_full_unstemmed | Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title_short | Crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(III) |
| title_sort | crystal structure of tetrakis(acetylacetonato)dichloridodi-μ(3)-methanolato-tetra-μ(2)-methanolato-tetrairon(iii) |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571370/ https://www.ncbi.nlm.nih.gov/pubmed/26396769 http://dx.doi.org/10.1107/S2056989015013535 |
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