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Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate

In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl­sulfan­yl)benzoate anio...

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Detalles Bibliográficos
Autores principales: Zhu, Jin-Li, Li, Jian-hua, Wang, Miao, Jiang, Guo-Min, Jiang, Guo-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571371/
https://www.ncbi.nlm.nih.gov/pubmed/26396770
http://dx.doi.org/10.1107/S205698901501364X
Descripción
Sumario:In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl­sulfan­yl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supra­molecular network is formed through weak inter­molecular C—H⋯O and C—H⋯S inter­actions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methyl­sulfan­yl)benzoate ligands.