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Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methylsulfanyl)benzoate anio...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571371/ https://www.ncbi.nlm.nih.gov/pubmed/26396770 http://dx.doi.org/10.1107/S205698901501364X |
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author | Zhu, Jin-Li Li, Jian-hua Wang, Miao Jiang, Guo-Min Jiang, Guo-Qing |
author_facet | Zhu, Jin-Li Li, Jian-hua Wang, Miao Jiang, Guo-Min Jiang, Guo-Qing |
author_sort | Zhu, Jin-Li |
collection | PubMed |
description | In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methylsulfanyl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supramolecular network is formed through weak intermolecular C—H⋯O and C—H⋯S interactions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methylsulfanyl)benzoate ligands. |
format | Online Article Text |
id | pubmed-4571371 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45713712015-09-22 Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate Zhu, Jin-Li Li, Jian-hua Wang, Miao Jiang, Guo-Min Jiang, Guo-Qing Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methylsulfanyl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supramolecular network is formed through weak intermolecular C—H⋯O and C—H⋯S interactions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methylsulfanyl)benzoate ligands. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571371/ /pubmed/26396770 http://dx.doi.org/10.1107/S205698901501364X Text en © Zhu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Zhu, Jin-Li Li, Jian-hua Wang, Miao Jiang, Guo-Min Jiang, Guo-Qing Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate |
title | Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2)
N,N′)copper(II) monohydrate |
title_full | Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2)
N,N′)copper(II) monohydrate |
title_fullStr | Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2)
N,N′)copper(II) monohydrate |
title_full_unstemmed | Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2)
N,N′)copper(II) monohydrate |
title_short | Crystal structure of aquabis[4-(methylsulfanyl)benzoato-κO](1,10-phenanthroline-κ(2)
N,N′)copper(II) monohydrate |
title_sort | crystal structure of aquabis[4-(methylsulfanyl)benzoato-κo](1,10-phenanthroline-κ(2)
n,n′)copper(ii) monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571371/ https://www.ncbi.nlm.nih.gov/pubmed/26396770 http://dx.doi.org/10.1107/S205698901501364X |
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