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Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate

In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl­sulfan­yl)benzoate anio...

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Autores principales: Zhu, Jin-Li, Li, Jian-hua, Wang, Miao, Jiang, Guo-Min, Jiang, Guo-Qing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571371/
https://www.ncbi.nlm.nih.gov/pubmed/26396770
http://dx.doi.org/10.1107/S205698901501364X
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author Zhu, Jin-Li
Li, Jian-hua
Wang, Miao
Jiang, Guo-Min
Jiang, Guo-Qing
author_facet Zhu, Jin-Li
Li, Jian-hua
Wang, Miao
Jiang, Guo-Min
Jiang, Guo-Qing
author_sort Zhu, Jin-Li
collection PubMed
description In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl­sulfan­yl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supra­molecular network is formed through weak inter­molecular C—H⋯O and C—H⋯S inter­actions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methyl­sulfan­yl)benzoate ligands.
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spelling pubmed-45713712015-09-22 Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate Zhu, Jin-Li Li, Jian-hua Wang, Miao Jiang, Guo-Min Jiang, Guo-Qing Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Cu(C(8)H(7)O(2)S)(2)(C(12)H(8)N(2))(H(2)O)]·H(2)O, the central Cu(II) atom is five-coordinated in a slightly distorted square-pyramidal environment by two N atoms from a 1,10-phenanthroline ligand, one O atom from the carboxylate group of one 4-(methyl­sulfan­yl)benzoate anion and one water O atom in the equatorial plane while the apical position is occupied by the O atom of a carboxylate group of the second anion. In the crystal, a three-dimensional supra­molecular network is formed through weak inter­molecular C—H⋯O and C—H⋯S inter­actions and π-stacking between the 1,10-phenanthroline ligand and the aromatic rings of symmetry-related 4-(methyl­sulfan­yl)benzoate ligands. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571371/ /pubmed/26396770 http://dx.doi.org/10.1107/S205698901501364X Text en © Zhu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Zhu, Jin-Li
Li, Jian-hua
Wang, Miao
Jiang, Guo-Min
Jiang, Guo-Qing
Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_full Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_fullStr Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_full_unstemmed Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_short Crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κO](1,10-phenanthroline-κ(2) N,N′)copper(II) monohydrate
title_sort crystal structure of aqua­bis­[4-(methyl­sulfan­yl)benzoato-κo](1,10-phenanthroline-κ(2) n,n′)copper(ii) monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571371/
https://www.ncbi.nlm.nih.gov/pubmed/26396770
http://dx.doi.org/10.1107/S205698901501364X
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