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Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate

The title compound, K(+)·C(5)H(11)O(8)S(−)·H(2)O [systematic name: potassium (1S,2S,3S,4R)-1,2,3,4,5-penta­hydroxy­pentane-1-sulfonate monohydrate], formed by reaction of d-lyxose with potassium hydrogen sulfite in water, crystallizes as colourless square prisms. The anion has an open-chain structur...

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Autores principales: Haines, Alan H., Hughes, David L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571375/
https://www.ncbi.nlm.nih.gov/pubmed/26396774
http://dx.doi.org/10.1107/S2056989015014139
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author Haines, Alan H.
Hughes, David L.
author_facet Haines, Alan H.
Hughes, David L.
author_sort Haines, Alan H.
collection PubMed
description The title compound, K(+)·C(5)H(11)O(8)S(−)·H(2)O [systematic name: potassium (1S,2S,3S,4R)-1,2,3,4,5-penta­hydroxy­pentane-1-sulfonate monohydrate], formed by reaction of d-lyxose with potassium hydrogen sulfite in water, crystallizes as colourless square prisms. The anion has an open-chain structure in which the S atom, the C atoms of the sugar chain and the oxygen atom of the hy­droxy­methyl group form an essentially all-trans chain with the corresponding torsion angles lying between 178.61 (12) and 157.75 (10)°. A three-dimensional bonding network exists in the crystal structure involving coordination of two crystallographically independent potassium ions by O atoms (one cation being hexa- and the other octa-coordinate, with each lying on a twofold rotation axis), and extensive inter­molecular O—H⋯O hydrogen bonding.
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spelling pubmed-45713752015-09-22 Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate Haines, Alan H. Hughes, David L. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, K(+)·C(5)H(11)O(8)S(−)·H(2)O [systematic name: potassium (1S,2S,3S,4R)-1,2,3,4,5-penta­hydroxy­pentane-1-sulfonate monohydrate], formed by reaction of d-lyxose with potassium hydrogen sulfite in water, crystallizes as colourless square prisms. The anion has an open-chain structure in which the S atom, the C atoms of the sugar chain and the oxygen atom of the hy­droxy­methyl group form an essentially all-trans chain with the corresponding torsion angles lying between 178.61 (12) and 157.75 (10)°. A three-dimensional bonding network exists in the crystal structure involving coordination of two crystallographically independent potassium ions by O atoms (one cation being hexa- and the other octa-coordinate, with each lying on a twofold rotation axis), and extensive inter­molecular O—H⋯O hydrogen bonding. International Union of Crystallography 2015-07-31 /pmc/articles/PMC4571375/ /pubmed/26396774 http://dx.doi.org/10.1107/S2056989015014139 Text en © Haines and Hughes 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Haines, Alan H.
Hughes, David L.
Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title_full Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title_fullStr Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title_full_unstemmed Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title_short Crystal structure of potassium (1S)-d-lyxit-1-yl­sulfonate monohydrate
title_sort crystal structure of potassium (1s)-d-lyxit-1-yl­sulfonate monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571375/
https://www.ncbi.nlm.nih.gov/pubmed/26396774
http://dx.doi.org/10.1107/S2056989015014139
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