Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)

In the mol­ecular structure of the title compound, [NiCl(2)(C(7)H(12)N(2)S)(2)], the Ni(II) atom has a distorted tetra­hedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axi...

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Detalles Bibliográficos
Autores principales: Ahmida, Aziza, Flörke, Ulrich, Egold, Hans, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571377/
https://www.ncbi.nlm.nih.gov/pubmed/26396777
http://dx.doi.org/10.1107/S2056989015012281
Descripción
Sumario:In the mol­ecular structure of the title compound, [NiCl(2)(C(7)H(12)N(2)S)(2)], the Ni(II) atom has a distorted tetra­hedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl—Ni—Cl = 115.58 (3)° and S—Ni—S = 94.55 (3)°. All other angles at the central Ni(II) atom range from 109.46 (2) to 112.96 (2)°. The C—S—Ni angle is 99.91 (6)°. The planes of two imidazolium rings make a dihedral angle of 70.56 (6)°.

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