Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)

In the mol­ecular structure of the title compound, [NiCl(2)(C(7)H(12)N(2)S)(2)], the Ni(II) atom has a distorted tetra­hedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axi...

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Autores principales: Ahmida, Aziza, Flörke, Ulrich, Egold, Hans, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571377/
https://www.ncbi.nlm.nih.gov/pubmed/26396777
http://dx.doi.org/10.1107/S2056989015012281
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author Ahmida, Aziza
Flörke, Ulrich
Egold, Hans
Henkel, Gerald
author_facet Ahmida, Aziza
Flörke, Ulrich
Egold, Hans
Henkel, Gerald
author_sort Ahmida, Aziza
collection PubMed
description In the mol­ecular structure of the title compound, [NiCl(2)(C(7)H(12)N(2)S)(2)], the Ni(II) atom has a distorted tetra­hedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl—Ni—Cl = 115.58 (3)° and S—Ni—S = 94.55 (3)°. All other angles at the central Ni(II) atom range from 109.46 (2) to 112.96 (2)°. The C—S—Ni angle is 99.91 (6)°. The planes of two imidazolium rings make a dihedral angle of 70.56 (6)°.
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spelling pubmed-45713772015-09-22 Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II) Ahmida, Aziza Flörke, Ulrich Egold, Hans Henkel, Gerald Acta Crystallogr E Crystallogr Commun Data Reports In the mol­ecular structure of the title compound, [NiCl(2)(C(7)H(12)N(2)S)(2)], the Ni(II) atom has a distorted tetra­hedral geometry, coordinated by two Cl atoms [Ni—Cl= 2.2336 (6) Å] and two thione S atoms [Ni—S= 2.3024 (6) Å]. The angles at the Ni(II) cation, which lies on a twofold rotation axis, are Cl—Ni—Cl = 115.58 (3)° and S—Ni—S = 94.55 (3)°. All other angles at the central Ni(II) atom range from 109.46 (2) to 112.96 (2)°. The C—S—Ni angle is 99.91 (6)°. The planes of two imidazolium rings make a dihedral angle of 70.56 (6)°. International Union of Crystallography 2015-07-04 /pmc/articles/PMC4571377/ /pubmed/26396777 http://dx.doi.org/10.1107/S2056989015012281 Text en © Ahmida et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ahmida, Aziza
Flörke, Ulrich
Egold, Hans
Henkel, Gerald
Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title_full Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title_fullStr Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title_full_unstemmed Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title_short Crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1H-imidazol-2-ium-2-thiol­ate-κS)nickel(II)
title_sort crystal structure of di­chlorido­bis­(1,3,4,5-tetra­methyl-1h-imidazol-2-ium-2-thiol­ate-κs)nickel(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571377/
https://www.ncbi.nlm.nih.gov/pubmed/26396777
http://dx.doi.org/10.1107/S2056989015012281
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