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Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]

In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclo­butane-1,1-di­carboxyl­ate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis­(pyridin-4-yl)ethane ligands to form a three-dimensional poly...

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Detalles Bibliográficos
Autores principales: Lee, Do Nam, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/
https://www.ncbi.nlm.nih.gov/pubmed/26396779
http://dx.doi.org/10.1107/S2056989015013791
Descripción
Sumario:In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclo­butane-1,1-di­carboxyl­ate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis­(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis­(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octa­hedral and is built up by four carboxyl­ate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water mol­ecule are in a trans configuration. One carboxyl­ate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxyl­ate group coordinates two different Mn(II) atoms.