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Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional poly...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/ https://www.ncbi.nlm.nih.gov/pubmed/26396779 http://dx.doi.org/10.1107/S2056989015013791 |
Sumario: | In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octahedral and is built up by four carboxylate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water molecule are in a trans configuration. One carboxylate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxylate group coordinates two different Mn(II) atoms. |
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