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Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional poly...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/ https://www.ncbi.nlm.nih.gov/pubmed/26396779 http://dx.doi.org/10.1107/S2056989015013791 |
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author | Lee, Do Nam Kim, Youngmee |
author_facet | Lee, Do Nam Kim, Youngmee |
author_sort | Lee, Do Nam |
collection | PubMed |
description | In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octahedral and is built up by four carboxylate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water molecule are in a trans configuration. One carboxylate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxylate group coordinates two different Mn(II) atoms. |
format | Online Article Text |
id | pubmed-4571379 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45713792015-09-22 Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3) O,O′:O′′:O′′′)dimanganese(II)] Lee, Do Nam Kim, Youngmee Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclobutane-1,1-dicarboxylate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octahedral and is built up by four carboxylate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water molecule are in a trans configuration. One carboxylate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxylate group coordinates two different Mn(II) atoms. International Union of Crystallography 2015-07-25 /pmc/articles/PMC4571379/ /pubmed/26396779 http://dx.doi.org/10.1107/S2056989015013791 Text en © Lee and Kim 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Lee, Do Nam Kim, Youngmee Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3) O,O′:O′′:O′′′)dimanganese(II)] |
title | Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
O,O′:O′′:O′′′)dimanganese(II)] |
title_full | Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
O,O′:O′′:O′′′)dimanganese(II)] |
title_fullStr | Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
O,O′:O′′:O′′′)dimanganese(II)] |
title_full_unstemmed | Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
O,O′:O′′:O′′′)dimanganese(II)] |
title_short | Structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
N:N′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
O,O′:O′′:O′′′)dimanganese(II)] |
title_sort | structure of poly[diaqua[μ-1,2-bis(pyridin-4-yl)ethane-κ(2)
n:n′]bis(μ(3)-cyclobutane-1,1-dicarboxylato-κ(3)
o,o′:o′′:o′′′)dimanganese(ii)] |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/ https://www.ncbi.nlm.nih.gov/pubmed/26396779 http://dx.doi.org/10.1107/S2056989015013791 |
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