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Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]

In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclo­butane-1,1-di­carboxyl­ate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis­(pyridin-4-yl)ethane ligands to form a three-dimensional poly...

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Detalles Bibliográficos
Autores principales: Lee, Do Nam, Kim, Youngmee
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/
https://www.ncbi.nlm.nih.gov/pubmed/26396779
http://dx.doi.org/10.1107/S2056989015013791
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author Lee, Do Nam
Kim, Youngmee
author_facet Lee, Do Nam
Kim, Youngmee
author_sort Lee, Do Nam
collection PubMed
description In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclo­butane-1,1-di­carboxyl­ate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis­(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis­(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octa­hedral and is built up by four carboxyl­ate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water mol­ecule are in a trans configuration. One carboxyl­ate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxyl­ate group coordinates two different Mn(II) atoms.
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spelling pubmed-45713792015-09-22 Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)] Lee, Do Nam Kim, Youngmee Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, [Mn(C(6)H(6)O(4))(C(12)H(12)N(2))(H(2)O)](n), the cyclo­butane-1,1-di­carboxyl­ate (cbdc) ligands bridge three Mn(II) ions, forming layers parallel to the ac plane. These layers are additionally connected by 1,2-bis­(pyridin-4-yl)ethane ligands to form a three-dimensional polymeric framework. An inversion centre is located at the mid-point of the central C—C bond of the 1,2-bis­(pyridin-4-yl)ethane ligand. The coordination geometry of the Mn(II) ion is distorted octa­hedral and is built up by four carboxyl­ate O atoms, one water O atom and a pyridyl N atom. The pyridine ligand and the coordinating water mol­ecule are in a trans configuration. One carboxyl­ate group of the cbdc ligand acts as a chelating ligand towards one Mn(II) atom, whereas the second carboxyl­ate group coordinates two different Mn(II) atoms. International Union of Crystallography 2015-07-25 /pmc/articles/PMC4571379/ /pubmed/26396779 http://dx.doi.org/10.1107/S2056989015013791 Text en © Lee and Kim 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lee, Do Nam
Kim, Youngmee
Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title_full Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title_fullStr Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title_full_unstemmed Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title_short Structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) N:N′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) O,O′:O′′:O′′′)dimanganese(II)]
title_sort structure of poly[di­aqua­[μ-1,2-bis­(pyri­din-4-yl)ethane-κ(2) n:n′]bis­(μ(3)-cyclo­butane-1,1-di­carboxyl­ato-κ(3) o,o′:o′′:o′′′)dimanganese(ii)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571379/
https://www.ncbi.nlm.nih.gov/pubmed/26396779
http://dx.doi.org/10.1107/S2056989015013791
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