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Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile
In the title compound, C(20)H(14)N(2)O(2), the hydroxybenzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571384/ https://www.ncbi.nlm.nih.gov/pubmed/26396784 http://dx.doi.org/10.1107/S2056989015012566 |
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author | Akkurt, Mehmet Horton, Peter N. Younes, Sabry H. H. Mohamed, Shaaban K. Albayati, Mustafa R. |
author_facet | Akkurt, Mehmet Horton, Peter N. Younes, Sabry H. H. Mohamed, Shaaban K. Albayati, Mustafa R. |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | In the title compound, C(20)H(14)N(2)O(2), the hydroxybenzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a supramolecular layer in the bc plane; N—H⋯π interactions also contribute to this arrangement. The layers are linked by weak by C—H⋯π and π–π [inter-centroid separation = 3.8713 (7) Å] interactions. |
format | Online Article Text |
id | pubmed-4571384 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45713842015-09-22 Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile Akkurt, Mehmet Horton, Peter N. Younes, Sabry H. H. Mohamed, Shaaban K. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(14)N(2)O(2), the hydroxybenzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and N—H⋯O hydrogen bonds link the molecules into a supramolecular layer in the bc plane; N—H⋯π interactions also contribute to this arrangement. The layers are linked by weak by C—H⋯π and π–π [inter-centroid separation = 3.8713 (7) Å] interactions. International Union of Crystallography 2015-07-04 /pmc/articles/PMC4571384/ /pubmed/26396784 http://dx.doi.org/10.1107/S2056989015012566 Text en © Akkurt et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Akkurt, Mehmet Horton, Peter N. Younes, Sabry H. H. Mohamed, Shaaban K. Albayati, Mustafa R. Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title | Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title_full | Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title_fullStr | Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title_full_unstemmed | Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title_short | Crystal structure of 3-amino-1-(4-hydroxyphenyl)-1H-benzo[f]chromene-2-carbonitrile |
title_sort | crystal structure of 3-amino-1-(4-hydroxyphenyl)-1h-benzo[f]chromene-2-carbonitrile |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571384/ https://www.ncbi.nlm.nih.gov/pubmed/26396784 http://dx.doi.org/10.1107/S2056989015012566 |
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