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Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile

In the title compound, C(20)H(14)N(2)O(2), the hy­droxy­benzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and...

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Autores principales: Akkurt, Mehmet, Horton, Peter N., Younes, Sabry H. H., Mohamed, Shaaban K., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571384/
https://www.ncbi.nlm.nih.gov/pubmed/26396784
http://dx.doi.org/10.1107/S2056989015012566
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author Akkurt, Mehmet
Horton, Peter N.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Albayati, Mustafa R.
author_facet Akkurt, Mehmet
Horton, Peter N.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Albayati, Mustafa R.
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(20)H(14)N(2)O(2), the hy­droxy­benzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular layer in the bc plane; N—H⋯π inter­actions also contribute to this arrangement. The layers are linked by weak by C—H⋯π and π–π [inter-centroid separation = 3.8713 (7) Å] inter­actions.
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spelling pubmed-45713842015-09-22 Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile Akkurt, Mehmet Horton, Peter N. Younes, Sabry H. H. Mohamed, Shaaban K. Albayati, Mustafa R. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(20)H(14)N(2)O(2), the hy­droxy­benzene ring is almost perpendicular to the mean plane of the naphthalene ring system, making a dihedral angle of 85.56 (4)°. The 4H-pyran ring fused with the naphthalene ring system has a flattened boat conformation. In the crystal, O—H⋯N and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular layer in the bc plane; N—H⋯π inter­actions also contribute to this arrangement. The layers are linked by weak by C—H⋯π and π–π [inter-centroid separation = 3.8713 (7) Å] inter­actions. International Union of Crystallography 2015-07-04 /pmc/articles/PMC4571384/ /pubmed/26396784 http://dx.doi.org/10.1107/S2056989015012566 Text en © Akkurt et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Akkurt, Mehmet
Horton, Peter N.
Younes, Sabry H. H.
Mohamed, Shaaban K.
Albayati, Mustafa R.
Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title_full Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title_fullStr Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title_full_unstemmed Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title_short Crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1H-benzo[f]chromene-2-carbo­nitrile
title_sort crystal structure of 3-amino-1-(4-hy­droxy­phen­yl)-1h-benzo[f]chromene-2-carbo­nitrile
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571384/
https://www.ncbi.nlm.nih.gov/pubmed/26396784
http://dx.doi.org/10.1107/S2056989015012566
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