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Crystal structure of sepaconitine, a C(19)-diterpenoid alkaloid from the roots of Aconitum sinomontanum Nakai
The title compound [systematic name: [(1α,14α,16β)-20-ethyl-8,9,10-trihydroxy-1,14,16-trimethoxyaconitan-4-yl 2-aminobenzoate], C(30)H(42)N(2)O(8), a natural C(19)-diterpenoid alkaloid, possesses an aconitane carbon skeleton with four six-membered rings and two five-membered rings. The fused ri...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571391/ https://www.ncbi.nlm.nih.gov/pubmed/26396791 http://dx.doi.org/10.1107/S205698901501258X |
Sumario: | The title compound [systematic name: [(1α,14α,16β)-20-ethyl-8,9,10-trihydroxy-1,14,16-trimethoxyaconitan-4-yl 2-aminobenzoate], C(30)H(42)N(2)O(8), a natural C(19)-diterpenoid alkaloid, possesses an aconitane carbon skeleton with four six-membered rings and two five-membered rings. The fused ring system contains two chair, one boat, one twist-boat and two envelope conformations. Intramolecular N—H⋯O hydrogen bonds are observed between the amino and carbonyl groups. The molecules are linked together via O—H⋯O hydrogen bonds, forming a three-dimensional framework. |
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