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Crystal structure of (Z)-3-[5-chloro-2-(prop-2-yn­yloxy)phen­yl]-3-hy­droxy-1-[4-(tri­fluoro­meth­yl)phen­yl]­prop-2-en-1-one

The title compound, C(19)H(12)ClF(3)O(3), obtained by the photochemical transformation of 2-[5-chloro-2-(prop-2-yn­yloxy)benzo­yl]-3-[4-(tri­fluoro­meth­yl)phen­yl]oxirane adopts a Z conformation with respect to the enolic C=C double bond. The dihedral angle between the benzene rings is 12.25 (16)°...

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Detalles Bibliográficos
Autores principales: Dalal, Aarti, Kamboj, Ramesh C., Kumar, Dinesh, Sharma, Mahendra Kumar, Selvarajan, Nagendran
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571394/
https://www.ncbi.nlm.nih.gov/pubmed/26396794
http://dx.doi.org/10.1107/S2056989015012748
Descripción
Sumario:The title compound, C(19)H(12)ClF(3)O(3), obtained by the photochemical transformation of 2-[5-chloro-2-(prop-2-yn­yloxy)benzo­yl]-3-[4-(tri­fluoro­meth­yl)phen­yl]oxirane adopts a Z conformation with respect to the enolic C=C double bond. The dihedral angle between the benzene rings is 12.25 (16)° and an intra­molecular O—H⋯O hydrogen bond closes an S(6) ring. An intra­molecular C—H⋯O inter­action also leads to an S(6) ring. In the crystal, very weak C—H⋯O inter­actions and short Cl⋯Cl contacts [3.3221 (16) Å] are seen, as well as weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.879 (2) Å].