Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one

In the title Schiff base, C(14)H(13)NO(4), which adopts the phenol–imine tautomeric form, the dihedral angle between the planes of the benzene and heterocyclic (r.m.s. deviation = 0.037 Å) rings is 53.31 (11)°. An intra­molecular O—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules ar...

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Autores principales: Djedouani, Amel, Boufas, Sihem, Cleymand, Franck, François, Michel, Fleutot, Solenne
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571398/
https://www.ncbi.nlm.nih.gov/pubmed/26396798
http://dx.doi.org/10.1107/S2056989015012840
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author Djedouani, Amel
Boufas, Sihem
Cleymand, Franck
François, Michel
Fleutot, Solenne
author_facet Djedouani, Amel
Boufas, Sihem
Cleymand, Franck
François, Michel
Fleutot, Solenne
author_sort Djedouani, Amel
collection PubMed
description In the title Schiff base, C(14)H(13)NO(4), which adopts the phenol–imine tautomeric form, the dihedral angle between the planes of the benzene and heterocyclic (r.m.s. deviation = 0.037 Å) rings is 53.31 (11)°. An intra­molecular O—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds to generate C(11) chains propagating in the [010] direction. A weak C—H⋯O link is also observed, leading to the formation of R (5) (5)(32) rings extending parallel to the (101) plane.
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spelling pubmed-45713982015-09-22 Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one Djedouani, Amel Boufas, Sihem Cleymand, Franck François, Michel Fleutot, Solenne Acta Crystallogr E Crystallogr Commun Data Reports In the title Schiff base, C(14)H(13)NO(4), which adopts the phenol–imine tautomeric form, the dihedral angle between the planes of the benzene and heterocyclic (r.m.s. deviation = 0.037 Å) rings is 53.31 (11)°. An intra­molecular O—H⋯N hydrogen bond closes an S(6) ring. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds to generate C(11) chains propagating in the [010] direction. A weak C—H⋯O link is also observed, leading to the formation of R (5) (5)(32) rings extending parallel to the (101) plane. International Union of Crystallography 2015-07-11 /pmc/articles/PMC4571398/ /pubmed/26396798 http://dx.doi.org/10.1107/S2056989015012840 Text en © Djedouani et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Djedouani, Amel
Boufas, Sihem
Cleymand, Franck
François, Michel
Fleutot, Solenne
Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title_full Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title_fullStr Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title_full_unstemmed Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title_short Crystal structure of (E)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2H-pyran-2-one
title_sort crystal structure of (e)-4-hy­droxy-3-{1-[(4-hy­droxy­phen­yl)imino]­eth­yl}-6-methyl-2h-pyran-2-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571398/
https://www.ncbi.nlm.nih.gov/pubmed/26396798
http://dx.doi.org/10.1107/S2056989015012840
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