Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate

The asymmetric unit of the title solvate, C(21)H(22)N(2)O(2)·CH(3)OH, contains one methanol solvent mol­ecule and one mol­ecule of the heterocycle that is built up by the fusion of four six-membered rings A, C, D, E and one five-membered ring B. The indole moiety (rings A and B) is essentially plana...

Descripción completa

Detalles Bibliográficos
Autores principales: Adizov, Shahobiddin M., Saidov, Abdusalom Sh., Turgunov, Kambarali K., Okmanov, Rasul Ya., Tashkhodjaev, Bakhodir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571404/
https://www.ncbi.nlm.nih.gov/pubmed/26396804
http://dx.doi.org/10.1107/S2056989015013286
Descripción
Sumario:The asymmetric unit of the title solvate, C(21)H(22)N(2)O(2)·CH(3)OH, contains one methanol solvent mol­ecule and one mol­ecule of the heterocycle that is built up by the fusion of four six-membered rings A, C, D, E and one five-membered ring B. The indole moiety (rings A and B) is essentially planar, with an r.m.s. deviation of 0.013 Å, whereas rings C and D adopt a twisted conformation with a trans-ring junction. In the crystal, two heterocyclic mol­ecules are associated with two methanol mol­ecules through mutual N—H⋯O and O—H⋯N hydrogen bonds, forming a centrosymmetric dimer.

Ejemplares similares