Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate

The asymmetric unit of the title solvate, C(21)H(22)N(2)O(2)·CH(3)OH, contains one methanol solvent mol­ecule and one mol­ecule of the heterocycle that is built up by the fusion of four six-membered rings A, C, D, E and one five-membered ring B. The indole moiety (rings A and B) is essentially plana...

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Autores principales: Adizov, Shahobiddin M., Saidov, Abdusalom Sh., Turgunov, Kambarali K., Okmanov, Rasul Ya., Tashkhodjaev, Bakhodir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571404/
https://www.ncbi.nlm.nih.gov/pubmed/26396804
http://dx.doi.org/10.1107/S2056989015013286
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author Adizov, Shahobiddin M.
Saidov, Abdusalom Sh.
Turgunov, Kambarali K.
Okmanov, Rasul Ya.
Tashkhodjaev, Bakhodir
author_facet Adizov, Shahobiddin M.
Saidov, Abdusalom Sh.
Turgunov, Kambarali K.
Okmanov, Rasul Ya.
Tashkhodjaev, Bakhodir
author_sort Adizov, Shahobiddin M.
collection PubMed
description The asymmetric unit of the title solvate, C(21)H(22)N(2)O(2)·CH(3)OH, contains one methanol solvent mol­ecule and one mol­ecule of the heterocycle that is built up by the fusion of four six-membered rings A, C, D, E and one five-membered ring B. The indole moiety (rings A and B) is essentially planar, with an r.m.s. deviation of 0.013 Å, whereas rings C and D adopt a twisted conformation with a trans-ring junction. In the crystal, two heterocyclic mol­ecules are associated with two methanol mol­ecules through mutual N—H⋯O and O—H⋯N hydrogen bonds, forming a centrosymmetric dimer.
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spelling pubmed-45714042015-09-22 Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate Adizov, Shahobiddin M. Saidov, Abdusalom Sh. Turgunov, Kambarali K. Okmanov, Rasul Ya. Tashkhodjaev, Bakhodir Acta Crystallogr E Crystallogr Commun Data Reports The asymmetric unit of the title solvate, C(21)H(22)N(2)O(2)·CH(3)OH, contains one methanol solvent mol­ecule and one mol­ecule of the heterocycle that is built up by the fusion of four six-membered rings A, C, D, E and one five-membered ring B. The indole moiety (rings A and B) is essentially planar, with an r.m.s. deviation of 0.013 Å, whereas rings C and D adopt a twisted conformation with a trans-ring junction. In the crystal, two heterocyclic mol­ecules are associated with two methanol mol­ecules through mutual N—H⋯O and O—H⋯N hydrogen bonds, forming a centrosymmetric dimer. International Union of Crystallography 2015-07-15 /pmc/articles/PMC4571404/ /pubmed/26396804 http://dx.doi.org/10.1107/S2056989015013286 Text en © Adizov et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Adizov, Shahobiddin M.
Saidov, Abdusalom Sh.
Turgunov, Kambarali K.
Okmanov, Rasul Ya.
Tashkhodjaev, Bakhodir
Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title_full Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title_fullStr Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title_full_unstemmed Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title_short Crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
title_sort crystal structure of 2,3-dimeth­oxy-5,6,7,8,13,13a-hexa­hydro-6a,8-di­aza­indeno­[2,1-b]phenanthrene methanol monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571404/
https://www.ncbi.nlm.nih.gov/pubmed/26396804
http://dx.doi.org/10.1107/S2056989015013286
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