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Crystal structure of 1-benzyl-2-hydroxy-5-oxopyrrolidin-3-yl acetate
In the title compound, C(13)H(15)NO(4), the oxopyrrolidin-3-yl ring has an envelope conformation, with the C atom bearing the acetate group being the flap. The acetate and phenyl groups are inclined with respect to the central ring, forming dihedral angles of 50.20 (12) and 87.40 (9)°, respectively,...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571408/ https://www.ncbi.nlm.nih.gov/pubmed/26396808 http://dx.doi.org/10.1107/S2056989015013353 |
Sumario: | In the title compound, C(13)H(15)NO(4), the oxopyrrolidin-3-yl ring has an envelope conformation, with the C atom bearing the acetate group being the flap. The acetate and phenyl groups are inclined with respect to the central ring, forming dihedral angles of 50.20 (12) and 87.40 (9)°, respectively, with the least-squares plane through the ring. The dihedral angle between the acetate group and the phenyl ring is 63.22 (8)°, indicating a twisted conformation in the molecule. In the crystal, supramolecular chains along the b axis are formed by (hydroxy)O—H⋯O(ring carbonyl) hydrogen bonds. The chains are consolidated into the three-dimensional architecture by C—H⋯O interactions. |
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