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Crystal structure of 1-benzyl-2-hy­droxy-5-oxopyrrolidin-3-yl acetate

In the title compound, C(13)H(15)NO(4), the oxopyrrolidin-3-yl ring has an envelope conformation, with the C atom bearing the acetate group being the flap. The acetate and phenyl groups are inclined with respect to the central ring, forming dihedral angles of 50.20 (12) and 87.40 (9)°, respectively,...

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Detalles Bibliográficos
Autores principales: Caracelli, Ignez, Zukerman-Schpector, Julio, Stefani, Hélio A., Ali, Bakhat, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571408/
https://www.ncbi.nlm.nih.gov/pubmed/26396808
http://dx.doi.org/10.1107/S2056989015013353
Descripción
Sumario:In the title compound, C(13)H(15)NO(4), the oxopyrrolidin-3-yl ring has an envelope conformation, with the C atom bearing the acetate group being the flap. The acetate and phenyl groups are inclined with respect to the central ring, forming dihedral angles of 50.20 (12) and 87.40 (9)°, respectively, with the least-squares plane through the ring. The dihedral angle between the acetate group and the phenyl ring is 63.22 (8)°, indicating a twisted conformation in the mol­ecule. In the crystal, supra­molecular chains along the b axis are formed by (hy­droxy)O—H⋯O(ring carbon­yl) hydrogen bonds. The chains are consolidated into the three-dimensional architecture by C—H⋯O inter­actions.