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Crystal structure of pyriproxyfen
In the title compound {systematic name: 4-phenoxyphenyl (RS)-2-[(pyridin-2-yl)oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571411/ https://www.ncbi.nlm.nih.gov/pubmed/26396811 http://dx.doi.org/10.1107/S2056989015013481 |
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author | Kang, Gihaeng Kim, Jineun Park, Hyunjin Kim, Tae Ho |
author_facet | Kang, Gihaeng Kim, Jineun Park, Hyunjin Kim, Tae Ho |
author_sort | Kang, Gihaeng |
collection | PubMed |
description | In the title compound {systematic name: 4-phenoxyphenyl (RS)-2-[(pyridin-2-yl)oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6) and 82.14 (8)°, respectively. The conformation of the O—C—C—O linkage is gauche [torsion angle = −75.0 (2)°]. In the crystal, weak aromatic π–π stacking interactions [centroid–centroid separation = 3.8436 (13) Å] and C—H⋯π interactions link adjacent molecules, forming a three-dimensional network. |
format | Online Article Text |
id | pubmed-4571411 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45714112015-09-22 Crystal structure of pyriproxyfen Kang, Gihaeng Kim, Jineun Park, Hyunjin Kim, Tae Ho Acta Crystallogr E Crystallogr Commun Data Reports In the title compound {systematic name: 4-phenoxyphenyl (RS)-2-[(pyridin-2-yl)oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6) and 82.14 (8)°, respectively. The conformation of the O—C—C—O linkage is gauche [torsion angle = −75.0 (2)°]. In the crystal, weak aromatic π–π stacking interactions [centroid–centroid separation = 3.8436 (13) Å] and C—H⋯π interactions link adjacent molecules, forming a three-dimensional network. International Union of Crystallography 2015-07-22 /pmc/articles/PMC4571411/ /pubmed/26396811 http://dx.doi.org/10.1107/S2056989015013481 Text en © Kang et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Kang, Gihaeng Kim, Jineun Park, Hyunjin Kim, Tae Ho Crystal structure of pyriproxyfen |
title | Crystal structure of pyriproxyfen |
title_full | Crystal structure of pyriproxyfen |
title_fullStr | Crystal structure of pyriproxyfen |
title_full_unstemmed | Crystal structure of pyriproxyfen |
title_short | Crystal structure of pyriproxyfen |
title_sort | crystal structure of pyriproxyfen |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571411/ https://www.ncbi.nlm.nih.gov/pubmed/26396811 http://dx.doi.org/10.1107/S2056989015013481 |
work_keys_str_mv | AT kanggihaeng crystalstructureofpyriproxyfen AT kimjineun crystalstructureofpyriproxyfen AT parkhyunjin crystalstructureofpyriproxyfen AT kimtaeho crystalstructureofpyriproxyfen |