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Crystal structure of pyriproxyfen

In the title compound {systematic name: 4-phen­oxy­phenyl (RS)-2-[(pyridin-2-yl)­oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6...

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Detalles Bibliográficos
Autores principales: Kang, Gihaeng, Kim, Jineun, Park, Hyunjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571411/
https://www.ncbi.nlm.nih.gov/pubmed/26396811
http://dx.doi.org/10.1107/S2056989015013481
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author Kang, Gihaeng
Kim, Jineun
Park, Hyunjin
Kim, Tae Ho
author_facet Kang, Gihaeng
Kim, Jineun
Park, Hyunjin
Kim, Tae Ho
author_sort Kang, Gihaeng
collection PubMed
description In the title compound {systematic name: 4-phen­oxy­phenyl (RS)-2-[(pyridin-2-yl)­oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6) and 82.14 (8)°, respectively. The conformation of the O—C—C—O linkage is gauche [torsion angle = −75.0 (2)°]. In the crystal, weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.8436 (13) Å] and C—H⋯π inter­actions link adjacent mol­ecules, forming a three-dimensional network.
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spelling pubmed-45714112015-09-22 Crystal structure of pyriproxyfen Kang, Gihaeng Kim, Jineun Park, Hyunjin Kim, Tae Ho Acta Crystallogr E Crystallogr Commun Data Reports In the title compound {systematic name: 4-phen­oxy­phenyl (RS)-2-[(pyridin-2-yl)­oxy]propyl ether}, C(20)H(19)NO(3), which is a juvenile hormone mimic and insecticide, the dihedral angles between the plane of the central benene ring and those of the pendant pyridine ring and phenyl ring are 78.09 (6) and 82.14 (8)°, respectively. The conformation of the O—C—C—O linkage is gauche [torsion angle = −75.0 (2)°]. In the crystal, weak aromatic π–π stacking inter­actions [centroid–centroid separation = 3.8436 (13) Å] and C—H⋯π inter­actions link adjacent mol­ecules, forming a three-dimensional network. International Union of Crystallography 2015-07-22 /pmc/articles/PMC4571411/ /pubmed/26396811 http://dx.doi.org/10.1107/S2056989015013481 Text en © Kang et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kang, Gihaeng
Kim, Jineun
Park, Hyunjin
Kim, Tae Ho
Crystal structure of pyriproxyfen
title Crystal structure of pyriproxyfen
title_full Crystal structure of pyriproxyfen
title_fullStr Crystal structure of pyriproxyfen
title_full_unstemmed Crystal structure of pyriproxyfen
title_short Crystal structure of pyriproxyfen
title_sort crystal structure of pyriproxyfen
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571411/
https://www.ncbi.nlm.nih.gov/pubmed/26396811
http://dx.doi.org/10.1107/S2056989015013481
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