Crystal structure of metobromuron

The title compound [systematic name: 3-(4-bromo­phen­yl)-1-meth­oxy-1-methyl­urea], C(9)H(11)BrN(2)O(2), is a phenyl­urea herbicide. The dihedral angle between the plane of the urea group and that of the bromo­phenyl ring is 39.13 (10)°. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak C—H⋯π...

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Detalles Bibliográficos
Autores principales: Kang, Gihaeng, Kim, Jineun, Kwon, Eunjin, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571412/
https://www.ncbi.nlm.nih.gov/pubmed/26396812
http://dx.doi.org/10.1107/S205698901501347X
Descripción
Sumario:The title compound [systematic name: 3-(4-bromo­phen­yl)-1-meth­oxy-1-methyl­urea], C(9)H(11)BrN(2)O(2), is a phenyl­urea herbicide. The dihedral angle between the plane of the urea group and that of the bromo­phenyl ring is 39.13 (10)°. In the crystal, N—H⋯O and C—H⋯O hydrogen bonds and weak C—H⋯π inter­actions link adjacent mol­ecules, forming chains along the a-axis direction. In addition, short inter­molecular Br⋯Br contacts [3.648 (4) Å] are present, resulting in a two-dimensional network extending parallel to (101).

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