Cargando…
Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate
In the title compound, C(17)H(17)N O(4)S, the quinoline ring system is nearly planar, with a maximum deviation of 0.0496 (16) Å. A weak intramolecular C—H⋯O interaction is observed. In the crystal, C—H⋯O, S—H⋯N and π–π stacking interactions between the fused benzene ring of quinoline and the pyri...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571415/ https://www.ncbi.nlm.nih.gov/pubmed/26396815 http://dx.doi.org/10.1107/S2056989015013596 |
_version_ | 1782390336770801664 |
---|---|
author | Rihanabanu, Anitha, B. R. Meenakshi, T. G. Kumar, K. Mahesh Devarajegowda, H. C. |
author_facet | Rihanabanu, Anitha, B. R. Meenakshi, T. G. Kumar, K. Mahesh Devarajegowda, H. C. |
author_sort | Rihanabanu, |
collection | PubMed |
description | In the title compound, C(17)H(17)N O(4)S, the quinoline ring system is nearly planar, with a maximum deviation of 0.0496 (16) Å. A weak intramolecular C—H⋯O interaction is observed. In the crystal, C—H⋯O, S—H⋯N and π–π stacking interactions between the fused benzene ring of quinoline and the pyridine moieties [shortest centroid–centroid distance = 3.6754 (11) Å] are observed. Inversion-related weak C—H⋯O intermolecular interactions diagonally along [010], with R (2) (2)(10) ring motifs, and S—H⋯N intermolecular interactions diagonally along [100], with R (2) (2)(8) ring motifs, are present, forming a three-dimensional network structure. No classical hydrogen bonds are observed. |
format | Online Article Text |
id | pubmed-4571415 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2015 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-45714152015-09-22 Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate Rihanabanu, Anitha, B. R. Meenakshi, T. G. Kumar, K. Mahesh Devarajegowda, H. C. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(17)N O(4)S, the quinoline ring system is nearly planar, with a maximum deviation of 0.0496 (16) Å. A weak intramolecular C—H⋯O interaction is observed. In the crystal, C—H⋯O, S—H⋯N and π–π stacking interactions between the fused benzene ring of quinoline and the pyridine moieties [shortest centroid–centroid distance = 3.6754 (11) Å] are observed. Inversion-related weak C—H⋯O intermolecular interactions diagonally along [010], with R (2) (2)(10) ring motifs, and S—H⋯N intermolecular interactions diagonally along [100], with R (2) (2)(8) ring motifs, are present, forming a three-dimensional network structure. No classical hydrogen bonds are observed. International Union of Crystallography 2015-07-22 /pmc/articles/PMC4571415/ /pubmed/26396815 http://dx.doi.org/10.1107/S2056989015013596 Text en © Rihanabanu et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Rihanabanu, Anitha, B. R. Meenakshi, T. G. Kumar, K. Mahesh Devarajegowda, H. C. Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title | Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title_full | Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title_fullStr | Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title_full_unstemmed | Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title_short | Crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
title_sort | crystal structure of diethyl 2-[(2-sulfanylquinolin-3-yl)methylidene]malonate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571415/ https://www.ncbi.nlm.nih.gov/pubmed/26396815 http://dx.doi.org/10.1107/S2056989015013596 |
work_keys_str_mv | AT rihanabanu crystalstructureofdiethyl22sulfanylquinolin3ylmethylidenemalonate AT anithabr crystalstructureofdiethyl22sulfanylquinolin3ylmethylidenemalonate AT meenakshitg crystalstructureofdiethyl22sulfanylquinolin3ylmethylidenemalonate AT kumarkmahesh crystalstructureofdiethyl22sulfanylquinolin3ylmethylidenemalonate AT devarajegowdahc crystalstructureofdiethyl22sulfanylquinolin3ylmethylidenemalonate |