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Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate

In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.0383 (28) Å, and the piperidine ring adopts a chair conformation. The 2H-chromene ring makes dihedral angles of 32.89 (16) and 67.33 (8)°, respectively, with the mean planes of the...

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Autores principales: Roopashree, K. R., Meenakshi, T. G., Kumar, K. Mahesh, Kotresh, O., Devarajegowda, H. C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571421/
https://www.ncbi.nlm.nih.gov/pubmed/26396821
http://dx.doi.org/10.1107/S2056989015013699
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author Roopashree, K. R.
Meenakshi, T. G.
Kumar, K. Mahesh
Kotresh, O.
Devarajegowda, H. C.
author_facet Roopashree, K. R.
Meenakshi, T. G.
Kumar, K. Mahesh
Kotresh, O.
Devarajegowda, H. C.
author_sort Roopashree, K. R.
collection PubMed
description In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.0383 (28) Å, and the piperidine ring adopts a chair conformation. The 2H-chromene ring makes dihedral angles of 32.89 (16) and 67.33 (8)°, respectively, with the mean planes of the piperidine ring and the carbodi­thio­ate group. In the crystal, C—H⋯O and weak C—H⋯S hydrogen bonds link the mol­ecules into chains along [001]. The crystal structure also features C—H⋯π and π–π inter­actions, with a centroid–centroid distance of 3.7097 (17) Å.
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spelling pubmed-45714212015-09-22 Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate Roopashree, K. R. Meenakshi, T. G. Kumar, K. Mahesh Kotresh, O. Devarajegowda, H. C. Acta Crystallogr E Crystallogr Commun Data Reports In the title compound, C(17)H(19)NO(2)S(2), the 2H-chromene ring system is nearly planar, with a maximum deviation of 0.0383 (28) Å, and the piperidine ring adopts a chair conformation. The 2H-chromene ring makes dihedral angles of 32.89 (16) and 67.33 (8)°, respectively, with the mean planes of the piperidine ring and the carbodi­thio­ate group. In the crystal, C—H⋯O and weak C—H⋯S hydrogen bonds link the mol­ecules into chains along [001]. The crystal structure also features C—H⋯π and π–π inter­actions, with a centroid–centroid distance of 3.7097 (17) Å. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571421/ /pubmed/26396821 http://dx.doi.org/10.1107/S2056989015013699 Text en © Roopashree et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Roopashree, K. R.
Meenakshi, T. G.
Kumar, K. Mahesh
Kotresh, O.
Devarajegowda, H. C.
Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title_full Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title_fullStr Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title_full_unstemmed Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title_short Crystal structure of (7-methyl-2-oxo-2H-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
title_sort crystal structure of (7-methyl-2-oxo-2h-chromen-4-yl)methyl piperidine-1-carbo­di­thio­ate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571421/
https://www.ncbi.nlm.nih.gov/pubmed/26396821
http://dx.doi.org/10.1107/S2056989015013699
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