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Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one

The title compound, C(22)H(20)O(5), is composed of a hy­droxy­naphthyl ring and a tri­meth­oxy­phenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that o...

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Autores principales: Srividya, J., Reuben Jonathan, D., Revathi, B. K., Anbalagan, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571423/
https://www.ncbi.nlm.nih.gov/pubmed/26396823
http://dx.doi.org/10.1107/S2056989015013870
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author Srividya, J.
Reuben Jonathan, D.
Revathi, B. K.
Anbalagan, G.
author_facet Srividya, J.
Reuben Jonathan, D.
Revathi, B. K.
Anbalagan, G.
author_sort Srividya, J.
collection PubMed
description The title compound, C(22)H(20)O(5), is composed of a hy­droxy­naphthyl ring and a tri­meth­oxy­phenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that of the naphthyl system and benzene rings by 3.77 (14) and 18.01 (16)°, respectively. There is an intra­molecular O—H⋯O hydrogen bond present forming an S(6) ring motif. In the crystal, inversion-related mol­ecules are linked by a slipped-parallel π–π inter­action [inter­centroid distance = 3.8942 (13) Å, inter­planar distance = 3.478 (9) Å and slippage = 1.751 Å], and stack along the [101] direction. There are no other significant inter­molecular inter­actions present.
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spelling pubmed-45714232015-09-22 Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one Srividya, J. Reuben Jonathan, D. Revathi, B. K. Anbalagan, G. Acta Crystallogr E Crystallogr Commun Data Reports The title compound, C(22)H(20)O(5), is composed of a hy­droxy­naphthyl ring and a tri­meth­oxy­phenyl ring [the planes of which are inclined to one another by 21.61 (10)°] bridged by an unsaturated prop-2-en-1-one group. The mean plane of the prop-2-en-1-one group [–C(=O)—C=C–] is inclined to that of the naphthyl system and benzene rings by 3.77 (14) and 18.01 (16)°, respectively. There is an intra­molecular O—H⋯O hydrogen bond present forming an S(6) ring motif. In the crystal, inversion-related mol­ecules are linked by a slipped-parallel π–π inter­action [inter­centroid distance = 3.8942 (13) Å, inter­planar distance = 3.478 (9) Å and slippage = 1.751 Å], and stack along the [101] direction. There are no other significant inter­molecular inter­actions present. International Union of Crystallography 2015-07-29 /pmc/articles/PMC4571423/ /pubmed/26396823 http://dx.doi.org/10.1107/S2056989015013870 Text en © Srividya et al. 2015 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Srividya, J.
Reuben Jonathan, D.
Revathi, B. K.
Anbalagan, G.
Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title_full Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title_fullStr Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title_full_unstemmed Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title_short Crystal structure of (E)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
title_sort crystal structure of (e)-1-(1-hy­droxy­naphthalen-2-yl)-3-(2,3,4-tri­meth­oxy­phen­yl)prop-2-en-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4571423/
https://www.ncbi.nlm.nih.gov/pubmed/26396823
http://dx.doi.org/10.1107/S2056989015013870
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