Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps

Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard add...

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Autores principales: Kotha, Sambasivarao, Ravikumar, Ongolu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2015
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578369/
https://www.ncbi.nlm.nih.gov/pubmed/26425184
http://dx.doi.org/10.3762/bjoc.11.140
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author Kotha, Sambasivarao
Ravikumar, Ongolu
author_facet Kotha, Sambasivarao
Ravikumar, Ongolu
author_sort Kotha, Sambasivarao
collection PubMed
description Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard addition. Here, fused polycycles are assembled which are difficult to produce by conventional synthetic routes.
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spelling pubmed-45783692015-09-30 Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps Kotha, Sambasivarao Ravikumar, Ongolu Beilstein J Org Chem Full Research Paper Atom efficient processes such as the Diels–Alder reaction (DA) and the ring-rearrangement metathesis (RRM) have been used to design new polycycles. In this regard, ruthenium alkylidene catalysts are effective in realizing the RRM of bis-norbornene derivatives prepared by DA reaction and Grignard addition. Here, fused polycycles are assembled which are difficult to produce by conventional synthetic routes. Beilstein-Institut 2015-07-27 /pmc/articles/PMC4578369/ /pubmed/26425184 http://dx.doi.org/10.3762/bjoc.11.140 Text en Copyright © 2015, Kotha and Ravikumar https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kotha, Sambasivarao
Ravikumar, Ongolu
Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_full Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_fullStr Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_full_unstemmed Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_short Design and synthesis of fused polycycles via Diels–Alder reaction and ring-rearrangement metathesis as key steps
title_sort design and synthesis of fused polycycles via diels–alder reaction and ring-rearrangement metathesis as key steps
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578369/
https://www.ncbi.nlm.nih.gov/pubmed/26425184
http://dx.doi.org/10.3762/bjoc.11.140
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