Cargando…
Why base-catalyzed isomerization of N-propargyl amides yields mostly allenamides rather than ynamides
The base-catalyzed isomerization of N-propargylamides or carbamates may furnish N-allenyl compounds (allenamides/allencarbamates) or further evolve to N-alkynyl compounds (ynamides or yncarbamates). The particular fate of this reaction varies from experiment to experiment and there is no clear rule...
Autor principal: | Navarro-Vázquez, Armando |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Beilstein-Institut
2015
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4578395/ https://www.ncbi.nlm.nih.gov/pubmed/26425200 http://dx.doi.org/10.3762/bjoc.11.156 |
Ejemplares similares
-
Direct synthesis of pentasubstituted pyrroles and hexasubstituted pyrrolines from propargyl sulfonylamides and allenamides
por: Ye, Changqing, et al.
Publicado: (2021) -
Facile synthesis of α-alkoxyl amides via scandium-catalyzed oxidative reaction between ynamides and alcohols
por: Zhang, Zhi-Xin, et al.
Publicado: (2018) -
Soft Propargylic
Deprotonation: Designed Ligand Enables
Au-Catalyzed Isomerization of Alkynes to 1,3-Dienes
por: Wang, Zhixun, et al.
Publicado: (2014) -
Impact of counteranions on N-heterocyclic carbene gold(i)-catalyzed cyclization of propargylic amide
por: Ali, Hafiz Saqib, et al.
Publicado: (2023) -
Silylium-Catalyzed
Regio- and Stereoselective Carbosilylation
of Ynamides with Allylic Trimethylsilanes
por: Yepes, Paz, et al.
Publicado: (2023)